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Organocatalytic enantioselective methodologies using Morita–Baylis–Hillman carbonates and acetates

Organocatalytic enantioselective methodologies using Morita–Baylis–Hillman carbonates and acetates
Organocatalytic enantioselective methodologies using Morita–Baylis–Hillman carbonates and acetates
Lately, the use of Morita–Baylis–Hillman carbonates and acetates in organocatalysis has grown exponentially. Since the pioneering work of Kim and coworkers until the last cycloadditions reported by Barbas, a plethora of new methodologies have been developed. The use of these compounds opens a new gate for the synthesis of C–C or C-heteroatom bonds in an enantioselective fashion and under mild conditions giving access to highly functionalized structures. In this review, we aim to cover these exciting reactions, paying special attention on the nature of the MBH adduct.
2044-4753
267-278
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441

Rios, Ramon (2012) Organocatalytic enantioselective methodologies using Morita–Baylis–Hillman carbonates and acetates. Catalysis Science & Technology, 2 (2), 267-278. (doi:10.1039/C1CY00387A).

Record type: Article

Abstract

Lately, the use of Morita–Baylis–Hillman carbonates and acetates in organocatalysis has grown exponentially. Since the pioneering work of Kim and coworkers until the last cycloadditions reported by Barbas, a plethora of new methodologies have been developed. The use of these compounds opens a new gate for the synthesis of C–C or C-heteroatom bonds in an enantioselective fashion and under mild conditions giving access to highly functionalized structures. In this review, we aim to cover these exciting reactions, paying special attention on the nature of the MBH adduct.

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More information

e-pub ahead of print date: 15 November 2011
Published date: 2012
Organisations: Chemistry

Identifiers

Local EPrints ID: 347682
URI: http://eprints.soton.ac.uk/id/eprint/347682
ISSN: 2044-4753
PURE UUID: ccb665a0-1e17-4c26-8697-f1df01f16789
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 29 Jan 2013 09:59
Last modified: 17 Dec 2019 01:38

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