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Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates

Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates
Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates
The highly enantioselective asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with bis(phenylsulfonyl)methane is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and enantioselectivities.
1477-0520
7986-7989
Companyó, Xavier
446791db-6e0a-40f9-9f20-3a8e8af9803c
Valero, Guillem
c5f692fe-3b07-4916-a4ec-23f78a45cc15
Ceban, Victor
418f8102-7ad6-4c3d-bf39-bd7ad9176292
Calvet, Teresa
07d81814-6e36-4aa0-9f28-db0c7e3b1849
Font-Bardía, Mercé
41a15fd1-a12e-4bfc-9d86-3e209684ed2b
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Companyó, Xavier
446791db-6e0a-40f9-9f20-3a8e8af9803c
Valero, Guillem
c5f692fe-3b07-4916-a4ec-23f78a45cc15
Ceban, Victor
418f8102-7ad6-4c3d-bf39-bd7ad9176292
Calvet, Teresa
07d81814-6e36-4aa0-9f28-db0c7e3b1849
Font-Bardía, Mercé
41a15fd1-a12e-4bfc-9d86-3e209684ed2b
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441

Companyó, Xavier, Valero, Guillem, Ceban, Victor, Calvet, Teresa, Font-Bardía, Mercé, Moyano, Albert and Rios, Ramon (2011) Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates. Organic & Biomolecular Chemistry, 9 (23), 7986-7989. (doi:10.1039/C1OB06308A). (PMID:21952909)

Record type: Article

Abstract

The highly enantioselective asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with bis(phenylsulfonyl)methane is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and enantioselectivities.

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More information

e-pub ahead of print date: 13 September 2011
Published date: 2011
Organisations: Chemistry

Identifiers

Local EPrints ID: 347686
URI: http://eprints.soton.ac.uk/id/eprint/347686
ISSN: 1477-0520
PURE UUID: e1abe915-e194-424f-b92f-1a7839bfb071
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 29 Jan 2013 10:08
Last modified: 10 Dec 2019 01:37

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