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Searching for untrodden paths in organocatalysis territory

Searching for untrodden paths in organocatalysis territory
Searching for untrodden paths in organocatalysis territory
In spite of the tremendous growth experienced by the field of asymmetric organocatalysis in the last decade, it is important to realize that we are still far away from having explored all of the possible pathways in organocatalysis ‘territory'; the application of the organocatalysis concept can still provide new catalysts and reactions for a variety of asymmetric organic transformations. To exemplify this assertion, we summarize the research performed in our laboratory over the past two years which has led to the development of new enantioselective approaches to organometallic compounds, to the desymmetrization of prochiral ketones, to functionalized cyclopropanes and piperidines, to fluorinated compounds, and to quaternary ?-amino acids, among others.
amines, asymmetric catalysis, tandem reactions, im­ines, nucleophilic additions
0936-5214
1883-1908
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Valero, Guillem
c5f692fe-3b07-4916-a4ec-23f78a45cc15
Companyó, Xavier
446791db-6e0a-40f9-9f20-3a8e8af9803c
Bravo, Natalia
b4885173-6065-4fb7-accb-392f7d05735b
Alba, Andrea-Nekane
e96df5c1-b984-45c5-9620-1d7f0cec8faf
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Valero, Guillem
c5f692fe-3b07-4916-a4ec-23f78a45cc15
Companyó, Xavier
446791db-6e0a-40f9-9f20-3a8e8af9803c
Bravo, Natalia
b4885173-6065-4fb7-accb-392f7d05735b
Alba, Andrea-Nekane
e96df5c1-b984-45c5-9620-1d7f0cec8faf

Rios, Ramon, Moyano, Albert, Valero, Guillem, Companyó, Xavier, Bravo, Natalia and Alba, Andrea-Nekane (2010) Searching for untrodden paths in organocatalysis territory. Synlett, 2010 (13), 1883-1908. (doi:10.1055/s-0030-1257988).

Record type: Article

Abstract

In spite of the tremendous growth experienced by the field of asymmetric organocatalysis in the last decade, it is important to realize that we are still far away from having explored all of the possible pathways in organocatalysis ‘territory'; the application of the organocatalysis concept can still provide new catalysts and reactions for a variety of asymmetric organic transformations. To exemplify this assertion, we summarize the research performed in our laboratory over the past two years which has led to the development of new enantioselective approaches to organometallic compounds, to the desymmetrization of prochiral ketones, to functionalized cyclopropanes and piperidines, to fluorinated compounds, and to quaternary ?-amino acids, among others.

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More information

Published date: 2010
Keywords: amines, asymmetric catalysis, tandem reactions, im­ines, nucleophilic additions
Organisations: Chemistry

Identifiers

Local EPrints ID: 347701
URI: http://eprints.soton.ac.uk/id/eprint/347701
ISSN: 0936-5214
PURE UUID: a85a57d4-42df-4151-8277-99e1992e98df
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 29 Jan 2013 11:30
Last modified: 03 Dec 2019 01:38

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