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Highly enantioselective fluoromalonate addition to ?,?-unsaturated aldehydes

Highly enantioselective fluoromalonate addition to ?,?-unsaturated aldehydes
Highly enantioselective fluoromalonate addition to ?,?-unsaturated aldehydes
A highly enantioselective organocatalytic fluoromalonate addition to ?,?-unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available secondary amines, affording the corresponding 1,4-adducts with high yields and enantioselectivities.
0040-4039
5021-5024
Companyó, Xavier
446791db-6e0a-40f9-9f20-3a8e8af9803c
Hejnová, Monika
0d741182-e661-4f00-97d0-781a5114282a
Kamlar, Martin
4cb85f32-9d4a-4beb-9b8a-db0e8e1f0ab0
Vesely, Jan
1853ff19-a906-4321-bd69-f7e434176fc3
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Companyó, Xavier
446791db-6e0a-40f9-9f20-3a8e8af9803c
Hejnová, Monika
0d741182-e661-4f00-97d0-781a5114282a
Kamlar, Martin
4cb85f32-9d4a-4beb-9b8a-db0e8e1f0ab0
Vesely, Jan
1853ff19-a906-4321-bd69-f7e434176fc3
Moyano, Albert
07f92405-40f4-4fc4-97b3-9bd5c9c14baa
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441

Companyó, Xavier, Hejnová, Monika, Kamlar, Martin, Vesely, Jan, Moyano, Albert and Rios, Ramon (2009) Highly enantioselective fluoromalonate addition to ?,?-unsaturated aldehydes. Tetrahedron Letters, 50 (35), 5021-5024. (doi:10.1016/j.tetlet.2009.06.092).

Record type: Article

Abstract

A highly enantioselective organocatalytic fluoromalonate addition to ?,?-unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available secondary amines, affording the corresponding 1,4-adducts with high yields and enantioselectivities.

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Published date: 2 September 2009
Organisations: Chemistry
Learn more about Chemistry research

Identifiers

Local EPrints ID: 347729
URI: http://eprints.soton.ac.uk/id/eprint/347729
DOI: doi:10.1016/j.tetlet.2009.06.092
ISSN: 0040-4039
PURE UUID: b3d30d30-9e7d-4d2b-ba39-58b4af84bbf2
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 29 Jan 2013 13:23
Last modified: 14 Mar 2024 12:51

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Contributors

Author: Xavier Companyó
Author: Monika Hejnová
Author: Martin Kamlar
Author: Jan Vesely
Author: Albert Moyano
Author: Ramon Rios ORCID iD

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