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The holy grail of organocatalysis: intermolecular ?-alkylation of aldehydes

The holy grail of organocatalysis: intermolecular ?-alkylation of aldehydes
The holy grail of organocatalysis: intermolecular ?-alkylation of aldehydes
Organocatalytic intermolecular ?-alkylation has been accomplished. The groups of Melchiorre and Cozzi have recently reported the realization of this long-time goal in organocatalysis, by the crucial use of stabilized carbocations. Alkylated products are obtained in good yields and with moderate to good enantioselectivities.
alkylation, carbocations, enantioselectivity, organocatalysis, synthetic methods
1867-3880
437-439
Alba, Andrea-Nekane
e96df5c1-b984-45c5-9620-1d7f0cec8faf
Viciano, Monica
57a5b8e6-9de2-4140-b5b6-e3d08d274129
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Alba, Andrea-Nekane
e96df5c1-b984-45c5-9620-1d7f0cec8faf
Viciano, Monica
57a5b8e6-9de2-4140-b5b6-e3d08d274129
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441

Alba, Andrea-Nekane, Viciano, Monica and Rios, Ramon (2009) The holy grail of organocatalysis: intermolecular ?-alkylation of aldehydes. ChemCatChem, 1 (4), 437-439. (doi:10.1002/cctc.200900196).

Record type: Article

Abstract

Organocatalytic intermolecular ?-alkylation has been accomplished. The groups of Melchiorre and Cozzi have recently reported the realization of this long-time goal in organocatalysis, by the crucial use of stabilized carbocations. Alkylated products are obtained in good yields and with moderate to good enantioselectivities.

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More information

Published date: 7 December 2009
Keywords: alkylation, carbocations, enantioselectivity, organocatalysis, synthetic methods
Organisations: Chemistry
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Identifiers

Local EPrints ID: 347731
URI: http://eprints.soton.ac.uk/id/eprint/347731
DOI: doi:10.1002/cctc.200900196
ISSN: 1867-3880
PURE UUID: 758668bf-588a-4b11-8cce-a8c5da3fa5e7
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 29 Jan 2013 13:45
Last modified: 14 Mar 2024 12:51

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Contributors

Author: Andrea-Nekane Alba
Author: Monica Viciano
Author: Ramon Rios ORCID iD

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