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Nonlinear effects in asymmetric amino acid catalysis by multiple interconnected stereoselective catalytic networks

Nonlinear effects in asymmetric amino acid catalysis by multiple interconnected stereoselective catalytic networks
Nonlinear effects in asymmetric amino acid catalysis by multiple interconnected stereoselective catalytic networks
The generation of significant positive nonlinear effects in asymmetric amino acid catalysis under homogeneous conditions, which can be explained by the model for cooperative catalytic stereoselective pathways, is reported. The addition of an achiral aldehyde generated the multiple interconnected stereoselective catalytic network.
amino acids, asymmetric catalysis, density functional calculations, enantioselectivity, nonlinear effects
0947-6539
13935-13940
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Schyman, Patric
5d7da490-3da7-44f3-bf1b-c03315b9ff7a
Sundén, Henrik
fe114b08-1de1-4e88-9778-a9cddf3aa76d
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Ullah, Farman
c4e2d4ca-7d4f-4d87-8024-c09777cdffba
Chen, Li-Jun
03469049-e359-4022-91c1-b4389fad6d97
Laaksonen, Aatto
40221d34-4bef-4d44-affc-c7518b4bee35
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Schyman, Patric
5d7da490-3da7-44f3-bf1b-c03315b9ff7a
Sundén, Henrik
fe114b08-1de1-4e88-9778-a9cddf3aa76d
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Ullah, Farman
c4e2d4ca-7d4f-4d87-8024-c09777cdffba
Chen, Li-Jun
03469049-e359-4022-91c1-b4389fad6d97
Laaksonen, Aatto
40221d34-4bef-4d44-affc-c7518b4bee35
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac

Rios, Ramon, Schyman, Patric, Sundén, Henrik, Zhao, Gui-Ling, Ullah, Farman, Chen, Li-Jun, Laaksonen, Aatto and Córdova, Armando (2010) Nonlinear effects in asymmetric amino acid catalysis by multiple interconnected stereoselective catalytic networks. Chemistry - A European Journal, 16 (47), 13935-13940. (doi:10.1002/chem.201002249). (PMID:21082627)

Record type: Article

Abstract

The generation of significant positive nonlinear effects in asymmetric amino acid catalysis under homogeneous conditions, which can be explained by the model for cooperative catalytic stereoselective pathways, is reported. The addition of an achiral aldehyde generated the multiple interconnected stereoselective catalytic network.

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e-pub ahead of print date: 16 November 2010
Published date: 17 December 2010
Keywords: amino acids, asymmetric catalysis, density functional calculations, enantioselectivity, nonlinear effects
Organisations: Chemistry

Identifiers

Local EPrints ID: 347737
URI: http://eprints.soton.ac.uk/id/eprint/347737
ISSN: 0947-6539
PURE UUID: 3f31e4dc-0dd8-4c77-bc35-c670ee1123a9
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

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Date deposited: 29 Jan 2013 14:04
Last modified: 29 Oct 2019 01:40

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Contributors

Author: Ramon Rios ORCID iD
Author: Patric Schyman
Author: Henrik Sundén
Author: Gui-Ling Zhao
Author: Farman Ullah
Author: Li-Jun Chen
Author: Aatto Laaksonen
Author: Armando Córdova

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