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Similarity between the kinetic parameters of the buffer-mediated proton exchange reaction of a xanthenic derivative in its ground- and excited-state

Similarity between the kinetic parameters of the buffer-mediated proton exchange reaction of a xanthenic derivative in its ground- and excited-state
Similarity between the kinetic parameters of the buffer-mediated proton exchange reaction of a xanthenic derivative in its ground- and excited-state
Buffer-mediated proton exchange reactions of a xanthenic dye were studied in the ground and the excited state by single molecule and bulk fluorescence techniques, respectively. The rate constant obtained supported the uniformity of the process in the ground and the excited state, and the need of adequate character of the buffer species to be able to promote excited-state reactions.
1463-9076
323-327
Paredes, Jose M.
56f39307-ce21-4a3c-9ec5-61dfc850ab43
Orte, Angel
d841ace2-236b-4fcd-b29d-5cf59ebe5408
Crovetto, Luis
45d4cd97-3fe5-4498-a861-bc06492eb09d
Alvarez-Pez, Jose M.
6970f24c-ecb5-418b-9847-f7a6be1d91f2
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Ruedas-Rama, Maria J.
b6eb1a76-0df4-4e30-a9d1-35732ced3951
Talavera, Eva M.
e0319787-e90f-48dd-b89f-5c631bbe15a1
Paredes, Jose M.
56f39307-ce21-4a3c-9ec5-61dfc850ab43
Orte, Angel
d841ace2-236b-4fcd-b29d-5cf59ebe5408
Crovetto, Luis
45d4cd97-3fe5-4498-a861-bc06492eb09d
Alvarez-Pez, Jose M.
6970f24c-ecb5-418b-9847-f7a6be1d91f2
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Ruedas-Rama, Maria J.
b6eb1a76-0df4-4e30-a9d1-35732ced3951
Talavera, Eva M.
e0319787-e90f-48dd-b89f-5c631bbe15a1

Paredes, Jose M., Orte, Angel, Crovetto, Luis, Alvarez-Pez, Jose M., Rios, Ramon, Ruedas-Rama, Maria J. and Talavera, Eva M. (2010) Similarity between the kinetic parameters of the buffer-mediated proton exchange reaction of a xanthenic derivative in its ground- and excited-state. Physical Chemistry Chemical Physics, 12 (2), 323-327. (doi:10.1039/b917333c). (PMID:20023807)

Record type: Article

Abstract

Buffer-mediated proton exchange reactions of a xanthenic dye were studied in the ground and the excited state by single molecule and bulk fluorescence techniques, respectively. The rate constant obtained supported the uniformity of the process in the ground and the excited state, and the need of adequate character of the buffer species to be able to promote excited-state reactions.

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e-pub ahead of print date: 4 November 2009
Published date: 2010
Organisations: Chemistry

Identifiers

Local EPrints ID: 347739
URI: http://eprints.soton.ac.uk/id/eprint/347739
ISSN: 1463-9076
PURE UUID: 66df2696-7198-4a2a-a1ef-43e6658fbeb4
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

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Date deposited: 29 Jan 2013 14:09
Last modified: 17 Dec 2019 01:38

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