One-pot catalytic asymmetric cascade synthesis of cycloheptane derivatives
One-pot catalytic asymmetric cascade synthesis of cycloheptane derivatives
A regiospecific, highly chemo-, diastereo-, and enantioselective one-pot catalytic cascade synthesis of cycloheptane derivatives is presented. In this chiral-amine-catalyzed asymmetric process, six new bonds and five new stereocenters were formed with excellent stereocontrol (>25:1 d.r. and 98- >99 ee).
asymmetric catalysis, cascade reaction, chiral amines, cycloaddition, cycloheptane derivatives
2693-2698
Vesely, Jan
1853ff19-a906-4321-bd69-f7e434176fc3
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Ibrahem, Ismail
3cbac9c1-431b-4a1f-8c41-92aa617254b0
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Eriksson, Lars
340ffb17-9c8e-468f-acba-13219dc22c37
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac
17 March 2008
Vesely, Jan
1853ff19-a906-4321-bd69-f7e434176fc3
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Ibrahem, Ismail
3cbac9c1-431b-4a1f-8c41-92aa617254b0
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Eriksson, Lars
340ffb17-9c8e-468f-acba-13219dc22c37
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac
Vesely, Jan, Rios, Ramon, Ibrahem, Ismail, Zhao, Gui-Ling, Eriksson, Lars and Córdova, Armando
(2008)
One-pot catalytic asymmetric cascade synthesis of cycloheptane derivatives.
Chemistry - A European Journal, 14 (9), .
(doi:10.1002/chem.200701918).
(PMID:18228546)
Abstract
A regiospecific, highly chemo-, diastereo-, and enantioselective one-pot catalytic cascade synthesis of cycloheptane derivatives is presented. In this chiral-amine-catalyzed asymmetric process, six new bonds and five new stereocenters were formed with excellent stereocontrol (>25:1 d.r. and 98- >99 ee).
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More information
e-pub ahead of print date: 28 January 2008
Published date: 17 March 2008
Keywords:
asymmetric catalysis, cascade reaction, chiral amines, cycloaddition, cycloheptane derivatives
Organisations:
Chemistry
Identifiers
Local EPrints ID: 347748
URI: http://eprints.soton.ac.uk/id/eprint/347748
ISSN: 0947-6539
PURE UUID: d60222cd-541d-42e4-b561-faf154c2f6f7
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Date deposited: 29 Jan 2013 14:26
Last modified: 14 Mar 2024 12:51
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Contributors
Author:
Jan Vesely
Author:
Ismail Ibrahem
Author:
Gui-Ling Zhao
Author:
Lars Eriksson
Author:
Armando Córdova
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