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One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines

One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines
One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines
A simple catalytic racemic synthesis of benzopyranes, benzothiopyranes and 1,2-dihydroquinolines is presented. The organocatalytic domino reactions between 2-heteroatom substituted aldehyde derivatives and ?,?-unsaturated aldehydes or ?,?-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding products in good to high yields.
0009-4293
219-223
Ibrahem, Ismail
3cbac9c1-431b-4a1f-8c41-92aa617254b0
Sundén, Henrik
fe114b08-1de1-4e88-9778-a9cddf3aa76d
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac
Ibrahem, Ismail
3cbac9c1-431b-4a1f-8c41-92aa617254b0
Sundén, Henrik
fe114b08-1de1-4e88-9778-a9cddf3aa76d
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac

Ibrahem, Ismail, Sundén, Henrik, Rios, Ramon, Zhao, Gui-Ling and Córdova, Armando (2007) One-pot pyrrolidine-catalyzed synthesis of benzopyrans, benzothiopyranes, and dihydroquinolidines. CHIMIA International Journal for Chemistry, 61 (5), 219-223. (doi:10.2533/chimia.2007.219).

Record type: Article

Abstract

A simple catalytic racemic synthesis of benzopyranes, benzothiopyranes and 1,2-dihydroquinolines is presented. The organocatalytic domino reactions between 2-heteroatom substituted aldehyde derivatives and ?,?-unsaturated aldehydes or ?,?-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding products in good to high yields.

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Published date: May 2007
Organisations: Chemistry
Learn more about Chemistry research

Identifiers

Local EPrints ID: 347990
URI: http://eprints.soton.ac.uk/id/eprint/347990
DOI: doi:10.2533/chimia.2007.219
ISSN: 0009-4293
PURE UUID: d736b671-b93b-45d2-a38f-e1ba5e6a3f25
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

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Date deposited: 05 Feb 2013 10:29
Last modified: 14 Mar 2024 12:54

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Contributors

Author: Ismail Ibrahem
Author: Henrik Sundén
Author: Ramon Rios ORCID iD
Author: Gui-Ling Zhao
Author: Armando Córdova

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