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A one-pot organocatalytic asymmetric entry to tetrahydrothioxanthenones

A one-pot organocatalytic asymmetric entry to tetrahydrothioxanthenones
A one-pot organocatalytic asymmetric entry to tetrahydrothioxanthenones
A simple catalytic asymmetric synthesis of tetrahydrothioxanthenones is presented. The organocatalytic enantioselective domino reactions between 2-mercaptobenzaldehyde and ?,?-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding tetrahydrothioxanthenones in high yields and moderate to good enantioselectivities.
0040-4039
8679-8682
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Sundén, Henrik
fe114b08-1de1-4e88-9778-a9cddf3aa76d
Ibrahem, Ismail
3cbac9c1-431b-4a1f-8c41-92aa617254b0
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac
Rios, Ramon
609bedf2-e886-4d62-a676-a32b6f8c1441
Sundén, Henrik
fe114b08-1de1-4e88-9778-a9cddf3aa76d
Ibrahem, Ismail
3cbac9c1-431b-4a1f-8c41-92aa617254b0
Zhao, Gui-Ling
106737c0-2aeb-4805-a8d7-496b1ce04322
Córdova, Armando
d2a1239f-708d-4f9c-bf7c-c095e9a27cac

Rios, Ramon, Sundén, Henrik, Ibrahem, Ismail, Zhao, Gui-Ling and Córdova, Armando (2006) A one-pot organocatalytic asymmetric entry to tetrahydrothioxanthenones. Tetrahedron Letters, 47 (49), 8679-8682. (doi:10.1016/j.tetlet.2006.10.028).

Record type: Article

Abstract

A simple catalytic asymmetric synthesis of tetrahydrothioxanthenones is presented. The organocatalytic enantioselective domino reactions between 2-mercaptobenzaldehyde and ?,?-unsaturated cyclic ketones proceed with excellent chemoselectivity to give the corresponding tetrahydrothioxanthenones in high yields and moderate to good enantioselectivities.

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More information

Published date: 4 December 2006
Organisations: Chemistry
Learn more about Chemistry research

Identifiers

Local EPrints ID: 347993
URI: http://eprints.soton.ac.uk/id/eprint/347993
DOI: doi:10.1016/j.tetlet.2006.10.028
ISSN: 0040-4039
PURE UUID: c0101f30-30ea-478c-aceb-a1522b2c3fc0
ORCID for Ramon Rios: ORCID iD orcid.org/0000-0002-3843-8521

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Date deposited: 05 Feb 2013 10:56
Last modified: 14 Mar 2024 12:54

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Contributors

Author: Ramon Rios ORCID iD
Author: Henrik Sundén
Author: Ismail Ibrahem
Author: Gui-Ling Zhao
Author: Armando Córdova

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