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First enantioselective organocatalytic addition of nitromethylphenylsulfone to enals. Enantioselective synthesis of cyclohexen carbaldehydes bearing 3 consecutive chiral centers

First enantioselective organocatalytic addition of nitromethylphenylsulfone to enals. Enantioselective synthesis of cyclohexen carbaldehydes bearing 3 consecutive chiral centers
First enantioselective organocatalytic addition of nitromethylphenylsulfone to enals. Enantioselective synthesis of cyclohexen carbaldehydes bearing 3 consecutive chiral centers
A highly enantioselectiveorganocatalyticnitromethylphenylsulfone addition to aliphatic ?,?-??unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available secondary amines, affording the cyclic compounds in moderate yields, good diastereoselectivities and excellent enantioselectivities.
1570-1794
Rios, R.
609bedf2-e886-4d62-a676-a32b6f8c1441
Vesely, J.
d1ec134c-93f7-4652-8dcf-84c26bbc17e5
Rios, R.
609bedf2-e886-4d62-a676-a32b6f8c1441
Vesely, J.
d1ec134c-93f7-4652-8dcf-84c26bbc17e5

(2013) First enantioselective organocatalytic addition of nitromethylphenylsulfone to enals. Enantioselective synthesis of cyclohexen carbaldehydes bearing 3 consecutive chiral centers. Current Organic Synthesis.

Record type: Article

Abstract

A highly enantioselectiveorganocatalyticnitromethylphenylsulfone addition to aliphatic ?,?-??unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available secondary amines, affording the cyclic compounds in moderate yields, good diastereoselectivities and excellent enantioselectivities.

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More information

Published date: January 2013
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Faculty of Natural and Environmental Sciences, Chemistry

Identifiers

Local EPrints ID: 348008
URI: http://eprints.soton.ac.uk/id/eprint/348008
ISSN: 1570-1794
PURE UUID: 4b6f18e8-d48b-48e9-a50c-0a7b778be753
ORCID for R. Rios: ORCID iD orcid.org/0000-0002-3843-8521

Catalogue record

Date deposited: 05 Feb 2013 11:53
Last modified: 06 Jun 2018 12:29

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