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Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials
Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials
Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na3MIIIF2(SO4)2, M = V, Mn, Fe, with a sheet-like structure formed of linked MIIIF2O4 and SO4 polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V
1359-7345
Wang, Qianlong
ee066382-8e61-4837-a4da-d183d32f2e42
Madsen, Alex
1d4678e9-0d8d-4d87-ba22-7fcc109570ce
Owen, John
067986ea-f3f3-4a83-bc87-7387cc5ac85d
Weller, Mark T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4
Wang, Qianlong
ee066382-8e61-4837-a4da-d183d32f2e42
Madsen, Alex
1d4678e9-0d8d-4d87-ba22-7fcc109570ce
Owen, John
067986ea-f3f3-4a83-bc87-7387cc5ac85d
Weller, Mark T.
36a60b56-049f-466c-a1d7-39d6b0d85ff4

Wang, Qianlong, Madsen, Alex, Owen, John and Weller, Mark T. (2013) Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials. Chemical Communications. (doi:10.1039/C3CC38897B).

Record type: Article

Abstract

Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na3MIIIF2(SO4)2, M = V, Mn, Fe, with a sheet-like structure formed of linked MIIIF2O4 and SO4 polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V

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More information

Published date: 4 February 2013
Organisations: Electrochemistry

Identifiers

Local EPrints ID: 348186
URI: http://eprints.soton.ac.uk/id/eprint/348186
DOI: doi:10.1039/C3CC38897B
ISSN: 1359-7345
PURE UUID: 6168f0f7-f72e-420c-b239-0e0ef29e8d9d
ORCID for John Owen: ORCID iD orcid.org/0000-0002-4938-3693

Catalogue record

Date deposited: 08 Feb 2013 09:47
Last modified: 15 Mar 2024 02:44

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Contributors

Author: Qianlong Wang
Author: Alex Madsen
Author: John Owen ORCID iD
Author: Mark T. Weller

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