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Homoleptic metal complexes of 4?-(5-pyrimidinyl)-2,2?:6?,2?-terpyridine: tetrafurcated expanded ligands

Homoleptic metal complexes of 4?-(5-pyrimidinyl)-2,2?:6?,2?-terpyridine: tetrafurcated expanded ligands
Homoleptic metal complexes of 4?-(5-pyrimidinyl)-2,2?:6?,2?-terpyridine: tetrafurcated expanded ligands
With iron(II) and ruthenium(II), 4?-(5-pyrimidinyl)-2,2?:6?,2?-terpyridine (L) preferentially coordinates through the tpy domain to give octahedral [ML2]2+ (M = Fe, Ru) complexes. Treatment of [RuL2][PF6]2 with CuCl2·2 H2O leads to {[Ru(2)2][CuCl2(OH2)][CuCl3]Cl·3MeCN·7H2O}n which exhibits a two-dimensional coordination network with copper(II) centres interconnecting [RuL2]2+ motifs. Magnetic susceptibility data for the material are consistent with a one-dimensional S = ½ antiferromagnetic chain.
1466-8033
986-990
Beves, Jonathon E.
354e102b-5b63-4f9b-9519-5ae5d99ac7c3
Constable, Edwin C.
d7da4205-ec75-47b5-a666-9ce90618069b
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd
Dunphy, Emma L.
6b44255a-ffdf-4c26-879d-da1e25f78540
Housecroft, Catherine E.
b63e2e1e-5ab0-4c20-858f-102cd71e5128
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Neuburger, Markus
332bf835-af5c-4431-a39c-f280d04783ea
Schaffner, Silvia
3f252531-0710-41ad-aa93-1282573d2a2a
Beves, Jonathon E.
354e102b-5b63-4f9b-9519-5ae5d99ac7c3
Constable, Edwin C.
d7da4205-ec75-47b5-a666-9ce90618069b
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd
Dunphy, Emma L.
6b44255a-ffdf-4c26-879d-da1e25f78540
Housecroft, Catherine E.
b63e2e1e-5ab0-4c20-858f-102cd71e5128
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Neuburger, Markus
332bf835-af5c-4431-a39c-f280d04783ea
Schaffner, Silvia
3f252531-0710-41ad-aa93-1282573d2a2a

Beves, Jonathon E., Constable, Edwin C., Decurtins, Silvio, Dunphy, Emma L., Housecroft, Catherine E., Keene, Tony D., Neuburger, Markus and Schaffner, Silvia (2008) Homoleptic metal complexes of 4?-(5-pyrimidinyl)-2,2?:6?,2?-terpyridine: tetrafurcated expanded ligands. CrystEngComm, 10, 986-990. (doi:10.1039/B807193B).

Record type: Article

Abstract

With iron(II) and ruthenium(II), 4?-(5-pyrimidinyl)-2,2?:6?,2?-terpyridine (L) preferentially coordinates through the tpy domain to give octahedral [ML2]2+ (M = Fe, Ru) complexes. Treatment of [RuL2][PF6]2 with CuCl2·2 H2O leads to {[Ru(2)2][CuCl2(OH2)][CuCl3]Cl·3MeCN·7H2O}n which exhibits a two-dimensional coordination network with copper(II) centres interconnecting [RuL2]2+ motifs. Magnetic susceptibility data for the material are consistent with a one-dimensional S = ½ antiferromagnetic chain.

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Published date: 2008
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 351070
URI: https://eprints.soton.ac.uk/id/eprint/351070
ISSN: 1466-8033
PURE UUID: ea6f5645-d39d-4be3-8bcd-f74201b80b48
ORCID for Tony D. Keene: ORCID iD orcid.org/0000-0003-2297-4327

Catalogue record

Date deposited: 16 Apr 2013 08:40
Last modified: 05 Nov 2019 01:37

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