The University of Southampton
University of Southampton Institutional Repository

Crystal engineering of a series of arylammonium copper(II) malonates

Crystal engineering of a series of arylammonium copper(II) malonates
Crystal engineering of a series of arylammonium copper(II) malonates
We present a series of eight layered copper(II) malonates, each with a {[HA](2)[Cu(II)(mal)(2)(H(2)O)]}(n) A-B-A layer structure, where A is an ammonium cation and 13 is an anionic copper malonate layer (x = 1 or 2; A = benzylamine, 1; S-(alpha)-methylbenzylamine, 2; 4-methylbenzylamine, 3; 4-carboxybenzylamine, 4; 4-trifluoromethylbenzylamine, 5; 4-trifluoromethoxybenzylamine, 6; phenylethylamine, 7; and 4-fluorophenylethylamine, 8). The ammonium cations used are primary amines based around benzylamine and phenylethylamine and include several different functional groups. The different amines give a large array of interlayer interactions, including van der Wail Is packing, hydrogen bonding, C-H center dot center dot center dot pi, pi-center dot center dot center dot pi, H center dot center dot center dot F, and F center dot center dot center dot F. interactions. [Despite the various functionalities on the arylammonium groups, the different interlayer packing interactions, and the differing degrees of hydration in the [Cu(II)(mal)(2)(H(2)O)(x)](2-) group, the anionic layer structure remains the same, indicating a high stability of this layer and its potential for further engineering of the organic layer components.
1528-7483
1854-1859
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Zimmermann, Iwan
c1ffc60d-700a-4757-865e-2395c1486f99
Neels, Antonia
a8d7f75b-c2c2-4d1f-bfb4-d538fd4c9073
Sereda, Olha
faf87206-8fd7-415b-ab6a-1203d668b97c
Hauser, Jürg
226b5d9d-61f7-4872-ae30-2c3aaffacaa1
Liu, Shi-Xia
546635e3-8931-436e-8456-298ac2a3134d
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Zimmermann, Iwan
c1ffc60d-700a-4757-865e-2395c1486f99
Neels, Antonia
a8d7f75b-c2c2-4d1f-bfb4-d538fd4c9073
Sereda, Olha
faf87206-8fd7-415b-ab6a-1203d668b97c
Hauser, Jürg
226b5d9d-61f7-4872-ae30-2c3aaffacaa1
Liu, Shi-Xia
546635e3-8931-436e-8456-298ac2a3134d
Decurtins, Silvio
331985a5-2121-47e4-a4b2-2fd09f8cabfd

Keene, Tony D., Zimmermann, Iwan, Neels, Antonia, Sereda, Olha, Hauser, Jürg, Liu, Shi-Xia and Decurtins, Silvio (2010) Crystal engineering of a series of arylammonium copper(II) malonates. Crystal Growth & Design, 10 (4), 1854-1859. (doi:10.1021/cg9015349).

Record type: Article

Abstract

We present a series of eight layered copper(II) malonates, each with a {[HA](2)[Cu(II)(mal)(2)(H(2)O)]}(n) A-B-A layer structure, where A is an ammonium cation and 13 is an anionic copper malonate layer (x = 1 or 2; A = benzylamine, 1; S-(alpha)-methylbenzylamine, 2; 4-methylbenzylamine, 3; 4-carboxybenzylamine, 4; 4-trifluoromethylbenzylamine, 5; 4-trifluoromethoxybenzylamine, 6; phenylethylamine, 7; and 4-fluorophenylethylamine, 8). The ammonium cations used are primary amines based around benzylamine and phenylethylamine and include several different functional groups. The different amines give a large array of interlayer interactions, including van der Wail Is packing, hydrogen bonding, C-H center dot center dot center dot pi, pi-center dot center dot center dot pi, H center dot center dot center dot F, and F center dot center dot center dot F. interactions. [Despite the various functionalities on the arylammonium groups, the different interlayer packing interactions, and the differing degrees of hydration in the [Cu(II)(mal)(2)(H(2)O)(x)](2-) group, the anionic layer structure remains the same, indicating a high stability of this layer and its potential for further engineering of the organic layer components.

Full text not available from this repository.

More information

Published date: 24 February 2010
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences

Identifiers

Local EPrints ID: 351385
URI: http://eprints.soton.ac.uk/id/eprint/351385
ISSN: 1528-7483
PURE UUID: 5e4f366e-3ed4-492d-949b-46e7e046260c
ORCID for Tony D. Keene: ORCID iD orcid.org/0000-0003-2297-4327

Catalogue record

Date deposited: 22 Apr 2013 10:07
Last modified: 19 Nov 2019 01:36

Export record

Altmetrics

Contributors

Author: Tony D. Keene ORCID iD
Author: Iwan Zimmermann
Author: Antonia Neels
Author: Olha Sereda
Author: Jürg Hauser
Author: Shi-Xia Liu
Author: Silvio Decurtins

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×