Magnetostructural investigations into an S=1/2 sheet and a tetranuclear butterfly cluster
Magnetostructural investigations into an S=1/2 sheet and a tetranuclear butterfly cluster
We present a detailed analysis of the magnetic properties of two Cu(II) coordination compounds with the tetrazole-1-acetate ligand (t1a), previously reported in literature by Yu et al. [Q. Yu, X. Zhang, H. Bian, H. Liang, B. Zhao, S. Yan, D. Liao, Cryst. Growth Des. 8 (2008) 1140] and simultaneously synthesised independently by ourselves. We focus on methods of describing the susceptibility and magnetisation of a ferromagnetically-coupled S = 1/2 square network (2) and a tetranuclear S = 1/2 'butterfly' cluster (4) as well as discussion of the energy levels of such a cluster.
copper(ii), molecular magnetism
2265-2269
Keene, Tony D.
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Deng, Yu-Heng
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Li, Feng-Ge
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Ding, Yan-Feng
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Wu, Biao
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Liu, Shi-Xia
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Ambrus, Christina
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Waldmann, Oliver
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Decurtins, Silvio
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Yang, Xiao-Juan
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15 May 2009
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Deng, Yu-Heng
7b9b6c41-30fe-4a15-b38c-1c0cc77e41e5
Li, Feng-Ge
001e161b-47b5-4b80-960d-f02ad944bea0
Ding, Yan-Feng
4d41682d-34ce-4f83-ba15-3cae103738a1
Wu, Biao
9e852bfc-2ba0-4bcd-93a2-09f145946a2e
Liu, Shi-Xia
546635e3-8931-436e-8456-298ac2a3134d
Ambrus, Christina
1daf47e1-777c-4d37-9d46-2bf4e7ae307b
Waldmann, Oliver
ae9850a7-3b8b-4f04-b955-1e4a4e257794
Decurtins, Silvio
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Yang, Xiao-Juan
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Keene, Tony D., Deng, Yu-Heng, Li, Feng-Ge, Ding, Yan-Feng, Wu, Biao, Liu, Shi-Xia, Ambrus, Christina, Waldmann, Oliver, Decurtins, Silvio and Yang, Xiao-Juan
(2009)
Magnetostructural investigations into an S=1/2 sheet and a tetranuclear butterfly cluster.
Inorganica Chimica Acta, 362 (7), .
(doi:10.1016/j.ica.2008.10.009).
Abstract
We present a detailed analysis of the magnetic properties of two Cu(II) coordination compounds with the tetrazole-1-acetate ligand (t1a), previously reported in literature by Yu et al. [Q. Yu, X. Zhang, H. Bian, H. Liang, B. Zhao, S. Yan, D. Liao, Cryst. Growth Des. 8 (2008) 1140] and simultaneously synthesised independently by ourselves. We focus on methods of describing the susceptibility and magnetisation of a ferromagnetically-coupled S = 1/2 square network (2) and a tetranuclear S = 1/2 'butterfly' cluster (4) as well as discussion of the energy levels of such a cluster.
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Published date: 15 May 2009
Keywords:
copper(ii), molecular magnetism
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 351391
URI: http://eprints.soton.ac.uk/id/eprint/351391
ISSN: 0020-1693
PURE UUID: bdd5ca8f-ea5a-4577-b9bc-723ceac57c1b
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Date deposited: 22 Apr 2013 10:53
Last modified: 14 Mar 2024 13:39
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Contributors
Author:
Tony D. Keene
Author:
Yu-Heng Deng
Author:
Feng-Ge Li
Author:
Yan-Feng Ding
Author:
Biao Wu
Author:
Shi-Xia Liu
Author:
Christina Ambrus
Author:
Oliver Waldmann
Author:
Silvio Decurtins
Author:
Xiao-Juan Yang
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