Poly[methylamine-mu-oxalato-copper(II)]
Poly[methylamine-mu-oxalato-copper(II)]
The six-coordinate copper(II) ions in the title compound, [Cu(C2O4)(CH5N)], experience a Jahn-Teller distortion. The structure is a two-dimensional coordination network, with three crystallographically independent oxalate ions, two of them centrosymmetric, bridging Cu-II ions in three different coordination modes. Each Cu ion is also coordinated by methyl-amine which is involved in both intra- and inter-layer hydrogen bonding.
m1373-m1375
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
2006
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Keene, Tony D., Hursthouse, Michael B. and Price, Daniel J.
(2006)
Poly[methylamine-mu-oxalato-copper(II)].
Acta Crystallographica Section E: Structure Reports Online, 62 (6), .
(doi:10.1107/S1600536806016679).
Abstract
The six-coordinate copper(II) ions in the title compound, [Cu(C2O4)(CH5N)], experience a Jahn-Teller distortion. The structure is a two-dimensional coordination network, with three crystallographically independent oxalate ions, two of them centrosymmetric, bridging Cu-II ions in three different coordination modes. Each Cu ion is also coordinated by methyl-amine which is involved in both intra- and inter-layer hydrogen bonding.
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Published date: 2006
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
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Local EPrints ID: 351393
URI: http://eprints.soton.ac.uk/id/eprint/351393
PURE UUID: 5eaccc0a-762b-45a9-822e-17e5308e5958
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Date deposited: 22 Apr 2013 13:40
Last modified: 03 Nov 2024 02:45
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Author:
Tony D. Keene
Author:
Daniel J. Price
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