Tetra-n-butylamine(carbonato-κ² O-2,O')cobalt(III)n-butylcarbamate dihydrate
Tetra-n-butylamine(carbonato-κ² O-2,O')cobalt(III)n-butylcarbamate dihydrate
The title compound, [Co(CO3)(C4H11N)(4)](C5H10NO2).2H(2)O, is a coordination complex with an N4O2 coordination sphere around the central Co-III ion. The small bite angle of the chelating carbonate causes a distortion of the octahedral geometry to an approximately C-2nu local symmetry. Hydrogen-bonding between the carbonate, carbamate and amine groups, and the water of crystallization, results in a complex two-dimensional network.
m381-m383
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
April 2004
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Keene, Tony D., Hursthouse, Michael B. and Price, Daniel J.
(2004)
Tetra-n-butylamine(carbonato-κ² O-2,O')cobalt(III)n-butylcarbamate dihydrate.
Acta Crystallographica Section E: Crystallographic Communications, 60 (4), .
(doi:10.1107/S1600536804005070).
Abstract
The title compound, [Co(CO3)(C4H11N)(4)](C5H10NO2).2H(2)O, is a coordination complex with an N4O2 coordination sphere around the central Co-III ion. The small bite angle of the chelating carbonate causes a distortion of the octahedral geometry to an approximately C-2nu local symmetry. Hydrogen-bonding between the carbonate, carbamate and amine groups, and the water of crystallization, results in a complex two-dimensional network.
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Published date: April 2004
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
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Local EPrints ID: 351395
URI: http://eprints.soton.ac.uk/id/eprint/351395
ISSN: 2056-9890
PURE UUID: 036cddc4-69f5-4757-84ce-5ef722db6a68
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Date deposited: 22 Apr 2013 13:48
Last modified: 03 Nov 2024 02:45
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Author:
Tony D. Keene
Author:
Daniel J. Price
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