The University of Southampton
University of Southampton Institutional Repository

Tetra-n-butylamine(carbonato-κ² O-2,O')cobalt(III)n-butylcarbamate dihydrate

Tetra-n-butylamine(carbonato-κ² O-2,O')cobalt(III)n-butylcarbamate dihydrate
Tetra-n-butylamine(carbonato-κ² O-2,O')cobalt(III)n-butylcarbamate dihydrate
The title compound, [Co(CO3)(C4H11N)(4)](C5H10NO2).2H(2)O, is a coordination complex with an N4O2 coordination sphere around the central Co-III ion. The small bite angle of the chelating carbonate causes a distortion of the octahedral geometry to an approximately C-2nu local symmetry. Hydrogen-bonding between the carbonate, carbamate and amine groups, and the water of crystallization, results in a complex two-dimensional network.
2056-9890
m381-m383
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192

Keene, Tony D., Hursthouse, Michael B. and Price, Daniel J. (2004) Tetra-n-butylamine(carbonato-κ² O-2,O')cobalt(III)n-butylcarbamate dihydrate. Acta Crystallographica Section E: Crystallographic Communications, 60 (4), m381-m383. (doi:10.1107/S1600536804005070).

Record type: Article

Abstract

The title compound, [Co(CO3)(C4H11N)(4)](C5H10NO2).2H(2)O, is a coordination complex with an N4O2 coordination sphere around the central Co-III ion. The small bite angle of the chelating carbonate causes a distortion of the octahedral geometry to an approximately C-2nu local symmetry. Hydrogen-bonding between the carbonate, carbamate and amine groups, and the water of crystallization, results in a complex two-dimensional network.

This record has no associated files available for download.

More information

Published date: April 2004
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 351395
URI: http://eprints.soton.ac.uk/id/eprint/351395
ISSN: 2056-9890
PURE UUID: 036cddc4-69f5-4757-84ce-5ef722db6a68
ORCID for Tony D. Keene: ORCID iD orcid.org/0000-0003-2297-4327

Catalogue record

Date deposited: 22 Apr 2013 13:48
Last modified: 14 Mar 2024 13:39

Export record

Altmetrics

Contributors

Author: Tony D. Keene ORCID iD
Author: Daniel J. Price

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×