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1,4-diazoniabicyclo 2.2.2 octane aquabis(oxalato-?² O,O')copper(II) dihydrate

1,4-diazoniabicyclo 2.2.2 octane aquabis(oxalato-?² O,O')copper(II) dihydrate
1,4-diazoniabicyclo 2.2.2 octane aquabis(oxalato-?² O,O')copper(II) dihydrate
The title compound, (C6H14N2)[Cu(C2O4)(2)(H2O)].2H(2)O, crystallizes in the space group P (1) over bar. In the solid state, the [Cu(ox)(2)(H2O)](2-) units (ox is oxalate, C2O4) dimerize to give a tetragonally distorted CuO6 coordination environment. Extensive hydrogen bonding between the oxalate, the coordinated water, the 1,4-diazoniabicyclo[2.2.2]octane dications ([dabcoH(2)](2+)) and the water of crystallization determines the crystal packing.
crystal-structures, anion
2056-9890
m378-m380
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192
Keene, Tony D.
fb859c26-6a1d-4c43-a15f-f329bc8d34d7
Hursthouse, Michael B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Price, Daniel J.
479ee5e3-2626-4abe-bffa-679d77ba5192

Keene, Tony D., Hursthouse, Michael B. and Price, Daniel J. (2004) 1,4-diazoniabicyclo 2.2.2 octane aquabis(oxalato-?² O,O')copper(II) dihydrate. Acta Crystallographica Section E: Crystallographic Communications, 60 (4), m378-m380. (doi:10.1107/S1600536804005033).

Record type: Article

Abstract

The title compound, (C6H14N2)[Cu(C2O4)(2)(H2O)].2H(2)O, crystallizes in the space group P (1) over bar. In the solid state, the [Cu(ox)(2)(H2O)](2-) units (ox is oxalate, C2O4) dimerize to give a tetragonally distorted CuO6 coordination environment. Extensive hydrogen bonding between the oxalate, the coordinated water, the 1,4-diazoniabicyclo[2.2.2]octane dications ([dabcoH(2)](2+)) and the water of crystallization determines the crystal packing.

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Published date: April 2004
Keywords: crystal-structures, anion
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 351396
URI: http://eprints.soton.ac.uk/id/eprint/351396
DOI: doi:10.1107/S1600536804005033
ISSN: 2056-9890
PURE UUID: c0cb5da3-e7ea-4353-9461-f1913b77061b
ORCID for Tony D. Keene: ORCID iD orcid.org/0000-0003-2297-4327

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Date deposited: 22 Apr 2013 13:53
Last modified: 03 Nov 2024 02:45

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Author: Tony D. Keene ORCID iD
Author: Michael B. Hursthouse
Author: Daniel J. Price

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