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Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex

Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex
Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex
Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [CuII8(dpt)4(OH)4(OAc)8]; OAc = acetate anion, and dpt? = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [CuII4(dpt)2(OH)(OMe)(OAc)4].
1359-7345
6229-6231
White, Nicholas G.
ebcbc4ca-7e2c-4af7-820d-366956f64762
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Joule, John A.
7ac77bb1-a905-4b77-acbf-2a555ca2623e
Brooker, Sally
2ee9681a-3ff7-41be-88c5-681f66b953ef
White, Nicholas G.
ebcbc4ca-7e2c-4af7-820d-366956f64762
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Joule, John A.
7ac77bb1-a905-4b77-acbf-2a555ca2623e
Brooker, Sally
2ee9681a-3ff7-41be-88c5-681f66b953ef

White, Nicholas G., Kitchen, Jonathan A., Joule, John A. and Brooker, Sally (2012) Copper-induced N–N bond cleavage results in an octanuclear expanded-core grid-like complex. Chemical Communications, 48 (50), 6229-6231. (doi:10.1039/c2cc32018e).

Record type: Article

Abstract

Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear [CuII8(dpt)4(OH)4(OAc)8]; OAc = acetate anion, and dpt? = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(II) acetate with dptH gives tetranuclear [CuII4(dpt)2(OH)(OMe)(OAc)4].

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More information

Published date: 24 April 2012
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences

Identifiers

Local EPrints ID: 352389
URI: http://eprints.soton.ac.uk/id/eprint/352389
ISSN: 1359-7345
PURE UUID: c0e543a1-4e9b-4ce7-a8f5-14e7f58baa5d
ORCID for Jonathan A. Kitchen: ORCID iD orcid.org/0000-0002-7139-5666

Catalogue record

Date deposited: 13 May 2013 11:15
Last modified: 16 Jul 2019 21:34

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