The University of Southampton
University of Southampton Institutional Repository

Pushing the limit: synthesis, photophysical and DNA binding studies of a NIR-emitting Ru(ii)-polypyridyl probe with ‘light switch’ behaviour

Pushing the limit: synthesis, photophysical and DNA binding studies of a NIR-emitting Ru(ii)-polypyridyl probe with ‘light switch’ behaviour
Pushing the limit: synthesis, photophysical and DNA binding studies of a NIR-emitting Ru(ii)-polypyridyl probe with ‘light switch’ behaviour
The new Ru(II) polypyridyl complex 1 was synthesised using microwave irradiation from the new polypyridyl ligand 2 ‘DipyTAP’, and its photophysical properties, and DNA binding abilities were investigated using various spectroscopic techniques; and 1 was shown to act as a ‘NIR molecular light switch’ for DNA with an emission window between 680 and 860 nm.

0300-9246
6607-6610
Elmes, Robert B.P.
0c1c9284-0678-450a-960f-dfb82a86d3e4
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Williams, D. Clive
1632daab-6295-4078-9bec-ec41c0a5353f
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50
Elmes, Robert B.P.
0c1c9284-0678-450a-960f-dfb82a86d3e4
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Williams, D. Clive
1632daab-6295-4078-9bec-ec41c0a5353f
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50

Elmes, Robert B.P., Kitchen, Jonathan A., Williams, D. Clive and Gunnlaugsson, Thorfinnur (2012) Pushing the limit: synthesis, photophysical and DNA binding studies of a NIR-emitting Ru(ii)-polypyridyl probe with ‘light switch’ behaviour. Dalton Transactions, 41 (22), 6607-6610. (doi:10.1039/c2dt00020b).

Record type: Article

Abstract

The new Ru(II) polypyridyl complex 1 was synthesised using microwave irradiation from the new polypyridyl ligand 2 ‘DipyTAP’, and its photophysical properties, and DNA binding abilities were investigated using various spectroscopic techniques; and 1 was shown to act as a ‘NIR molecular light switch’ for DNA with an emission window between 680 and 860 nm.

Full text not available from this repository.

More information

Published date: 5 April 2012
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences

Identifiers

Local EPrints ID: 352391
URI: http://eprints.soton.ac.uk/id/eprint/352391
ISSN: 0300-9246
PURE UUID: f0e43c91-4cbf-442c-a1e7-605749fb6e84
ORCID for Jonathan A. Kitchen: ORCID iD orcid.org/0000-0002-7139-5666

Catalogue record

Date deposited: 13 May 2013 11:57
Last modified: 16 Jul 2019 21:34

Export record

Altmetrics

Contributors

Author: Robert B.P. Elmes
Author: Jonathan A. Kitchen ORCID iD
Author: D. Clive Williams
Author: Thorfinnur Gunnlaugsson

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×