Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates"
Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates"
The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH3 CN give rise to the formation of lanthanide luminescent ‘half-helicates’ in 1 : 3 (Ln:ligand) stoichiometry; the formation of which was observed by monitoring the changes in the ground and the excited state properties of the ligands, and in the time-resolved Eu-centred and the CPL emission.
12056-12059
Lincheneau, Christophe
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Destribats, Carole
50ed9c61-736c-4a7d-977a-439eb27376f9
Barry, Dawn E.
73f19665-7389-4b80-a548-6e10f238a17a
Kitchen, Jonathan A.
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Peacock, Robert D.
cf938797-c8b4-43f6-b49d-6af680d03e3c
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50
7 December 2011
Lincheneau, Christophe
4e5bd816-7ca1-448d-b6de-8501f51176c2
Destribats, Carole
50ed9c61-736c-4a7d-977a-439eb27376f9
Barry, Dawn E.
73f19665-7389-4b80-a548-6e10f238a17a
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Peacock, Robert D.
cf938797-c8b4-43f6-b49d-6af680d03e3c
Gunnlaugsson, Thorfinnur
bbfcaaa6-2aca-47c9-9b7b-954442218f50
Lincheneau, Christophe, Destribats, Carole, Barry, Dawn E., Kitchen, Jonathan A., Peacock, Robert D. and Gunnlaugsson, Thorfinnur
(2011)
Lanthanide directed self-assembly synthesis and photophysical evaluation of chiral Eu(iii) luminescent “half-helicates".
Dalton Transactions, 40 (45), .
(doi:10.1039/c1dt11225b).
Abstract
The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH3 CN give rise to the formation of lanthanide luminescent ‘half-helicates’ in 1 : 3 (Ln:ligand) stoichiometry; the formation of which was observed by monitoring the changes in the ground and the excited state properties of the ligands, and in the time-resolved Eu-centred and the CPL emission.
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e-pub ahead of print date: 22 September 2011
Published date: 7 December 2011
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 352484
URI: http://eprints.soton.ac.uk/id/eprint/352484
ISSN: 0300-9246
PURE UUID: fb3dfecb-c0af-4753-a54c-9c017b58c182
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Date deposited: 14 May 2013 13:31
Last modified: 14 Mar 2024 13:53
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Contributors
Author:
Christophe Lincheneau
Author:
Carole Destribats
Author:
Dawn E. Barry
Author:
Jonathan A. Kitchen
Author:
Robert D. Peacock
Author:
Thorfinnur Gunnlaugsson
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