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Spin crossover in co-crystallised 2 ? 1 cis?trans [FeII(pldpt)2(NCS)2] occurs only in ? of the iron centres

Spin crossover in co-crystallised 2 ? 1 cis?trans [FeII(pldpt)2(NCS)2] occurs only in ? of the iron centres
Spin crossover in co-crystallised 2 ? 1 cis?trans [FeII(pldpt)2(NCS)2] occurs only in ? of the iron centres
The first spin crossover (SCO) active sample of co-crystallised stereoisomers (cis : trans, 2 : 1) is fully high spin (HS) at room temperature but displays temperature mediated SCO in which only a third of the iron(II) centres change spin state.
1359-7345
3200-3202
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Jameson, Guy N.L.
769b56b8-d317-4072-8852-235ae567620c
Tallon, Jeffery L.
222eab00-1b08-441c-8f77-a0a099a4f0f0
Brooker, Sally
2ee9681a-3ff7-41be-88c5-681f66b953ef
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Jameson, Guy N.L.
769b56b8-d317-4072-8852-235ae567620c
Tallon, Jeffery L.
222eab00-1b08-441c-8f77-a0a099a4f0f0
Brooker, Sally
2ee9681a-3ff7-41be-88c5-681f66b953ef

Kitchen, Jonathan A., Jameson, Guy N.L., Tallon, Jeffery L. and Brooker, Sally (2010) Spin crossover in co-crystallised 2 ? 1 cis?trans [FeII(pldpt)2(NCS)2] occurs only in ? of the iron centres. Chemical Communications, 46 (18), 3200-3202. (doi:10.1039/b927036a).

Record type: Article

Abstract

The first spin crossover (SCO) active sample of co-crystallised stereoisomers (cis : trans, 2 : 1) is fully high spin (HS) at room temperature but displays temperature mediated SCO in which only a third of the iron(II) centres change spin state.

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More information

e-pub ahead of print date: March 2010
Published date: 14 May 2010
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 352492
URI: http://eprints.soton.ac.uk/id/eprint/352492
DOI: doi:10.1039/b927036a
ISSN: 1359-7345
PURE UUID: f9807173-18a5-49a6-a606-dad0753c5d54
ORCID for Jonathan A. Kitchen: ORCID iD orcid.org/0000-0002-7139-5666

Catalogue record

Date deposited: 14 May 2013 13:57
Last modified: 14 Mar 2024 13:52

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Contributors

Author: Jonathan A. Kitchen ORCID iD
Author: Guy N.L. Jameson
Author: Jeffery L. Tallon
Author: Sally Brooker

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