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Proposal of the polymer chain alignment model

Proposal of the polymer chain alignment model
Proposal of the polymer chain alignment model
Four important models for explaining the properties that are observed in polymer based nanocomposites are the multi-core model, the intensity model, the interphase volume model and the double layer model. This paper outlines a new model, based on those four, which aims to explain certain properties that are considered unique to nanocomposites. The idea behind the polymer chain alignment model is that the material properties of nanocomposites strongly depend on processes prior to and during polymerization. It is assumed that a successful surface modification of nanoparticles leads to the formation of a rigid layer around each nanoparticle with properties differing from both host and filler material. The assumptions taken for the model were correlated with experimental data on epoxy based polymer nanocomposites.
978-1-4577-0985-2
624-627
Andritsch, T.
8681e640-e584-424e-a1f1-0d8b713de01c
Kochetov, R.
5647ae09-395a-4845-a4a9-51837a5c9aa0
Morshuis, P.H.F.
59248480-efdb-444e-b3f5-b39a3355315a
Smit, J.J.
21d902fe-6d70-4dff-ad29-3eb8146c0ea5
Andritsch, T.
8681e640-e584-424e-a1f1-0d8b713de01c
Kochetov, R.
5647ae09-395a-4845-a4a9-51837a5c9aa0
Morshuis, P.H.F.
59248480-efdb-444e-b3f5-b39a3355315a
Smit, J.J.
21d902fe-6d70-4dff-ad29-3eb8146c0ea5

Andritsch, T., Kochetov, R., Morshuis, P.H.F. and Smit, J.J. (2011) Proposal of the polymer chain alignment model. 2011 Annual Report Conference on Electrical Insulation and Dielectric Phenomena (CEIDP), Cancun, Mexico. 16 - 19 Oct 2011. pp. 624-627 . (doi:10.1109/CEIDP.2011.6232734).

Record type: Conference or Workshop Item (Paper)

Abstract

Four important models for explaining the properties that are observed in polymer based nanocomposites are the multi-core model, the intensity model, the interphase volume model and the double layer model. This paper outlines a new model, based on those four, which aims to explain certain properties that are considered unique to nanocomposites. The idea behind the polymer chain alignment model is that the material properties of nanocomposites strongly depend on processes prior to and during polymerization. It is assumed that a successful surface modification of nanoparticles leads to the formation of a rigid layer around each nanoparticle with properties differing from both host and filler material. The assumptions taken for the model were correlated with experimental data on epoxy based polymer nanocomposites.

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Published date: October 2011
Venue - Dates: 2011 Annual Report Conference on Electrical Insulation and Dielectric Phenomena (CEIDP), Cancun, Mexico, 2011-10-16 - 2011-10-19
Organisations: EEE

Identifiers

Local EPrints ID: 354472
URI: https://eprints.soton.ac.uk/id/eprint/354472
ISBN: 978-1-4577-0985-2
PURE UUID: 7c6c2d31-5ab2-4205-9ad6-73a725e34216
ORCID for T. Andritsch: ORCID iD orcid.org/0000-0002-3462-022X

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Date deposited: 30 Jul 2013 13:22
Last modified: 15 Oct 2019 00:35

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