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The indirect through-space F–F coupling in peri-difluoronaphthalene: is it anisotropic?

The indirect through-space F–F coupling in peri-difluoronaphthalene: is it anisotropic?
The indirect through-space F–F coupling in peri-difluoronaphthalene: is it anisotropic?
The 1H, 19F and 13C spectra have been obtained of a sample of peri-difluoronaphthalene dissolved in the nematic liquid crystalline solvent ZLI 1695. The 13C satellite spectra from the six, single-13C isotopomers at natural abundance in both the 1H and 19F spectra were identified and analysed to yield a set of residual total, anisotropic spin–spin couplings, Tij. This was achieved by first obtaining residual 13C–19F and 13C–1H couplings from a proton-encoded, 13C detected, local field 2D spectrum. The 45 values of THH, THF and TCH were used to obtain the structure of the molecule, and then to estimate whether there is a significant contribution from the component along the magnetic field, Janisoijzz, of the anisotropic, electron-mediated, spin–spin coupling tensors for 13C–19F and 19F–19F pairs. It is found that there is strong evidence for a significant contribution of JanisoFFzz to TFF but not for the 13C–19F pairs.
1463-9076
6534-6543
Emsley, J. W.
9d219d5e-28c0-4a8c-bf3d-1f78cd707c17
De Luca, G.
b190a7b3-3729-4118-b4c7-3a04da54f2b8
Lesage, A.
18ad673a-e0e4-4166-b97d-8f6c9fc3d548
Longeri, M.
39ff086e-7606-4a08-9296-1528644fdef5
Mallory, F. B.
d1a993ff-5680-4ac3-9bb0-f655edfc0b87
Mallory, C. W.
2283ae8f-79d9-4132-8889-74713e078334
Emsley, J. W.
9d219d5e-28c0-4a8c-bf3d-1f78cd707c17
De Luca, G.
b190a7b3-3729-4118-b4c7-3a04da54f2b8
Lesage, A.
18ad673a-e0e4-4166-b97d-8f6c9fc3d548
Longeri, M.
39ff086e-7606-4a08-9296-1528644fdef5
Mallory, F. B.
d1a993ff-5680-4ac3-9bb0-f655edfc0b87
Mallory, C. W.
2283ae8f-79d9-4132-8889-74713e078334

Emsley, J. W., De Luca, G., Lesage, A., Longeri, M., Mallory, F. B. and Mallory, C. W. (2008) The indirect through-space F–F coupling in peri-difluoronaphthalene: is it anisotropic? Physical Chemistry Chemical Physics, 10 (43), 6534-6543. (doi:10.1039/b809422e).

Record type: Article

Abstract

The 1H, 19F and 13C spectra have been obtained of a sample of peri-difluoronaphthalene dissolved in the nematic liquid crystalline solvent ZLI 1695. The 13C satellite spectra from the six, single-13C isotopomers at natural abundance in both the 1H and 19F spectra were identified and analysed to yield a set of residual total, anisotropic spin–spin couplings, Tij. This was achieved by first obtaining residual 13C–19F and 13C–1H couplings from a proton-encoded, 13C detected, local field 2D spectrum. The 45 values of THH, THF and TCH were used to obtain the structure of the molecule, and then to estimate whether there is a significant contribution from the component along the magnetic field, Janisoijzz, of the anisotropic, electron-mediated, spin–spin coupling tensors for 13C–19F and 19F–19F pairs. It is found that there is strong evidence for a significant contribution of JanisoFFzz to TFF but not for the 13C–19F pairs.

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Published date: 24 September 2008
Organisations: Magnetic Resonance

Identifiers

Local EPrints ID: 354706
URI: http://eprints.soton.ac.uk/id/eprint/354706
ISSN: 1463-9076
PURE UUID: 1e2d3605-9aa2-4337-8b18-436363ecee04

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Date deposited: 18 Jul 2013 10:53
Last modified: 14 Mar 2024 14:23

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Contributors

Author: J. W. Emsley
Author: G. De Luca
Author: A. Lesage
Author: M. Longeri
Author: F. B. Mallory
Author: C. W. Mallory

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