Nandagopal, Magesh and Utz, Marcel (2005) Quantification of global orientational order in organic solids by magic-angle spinning deuterium NMR with rotor synchronization. The Journal of Chemical Physics, 123 (24), 244504. (doi:10.1063/1.2132274).
Abstract
A new method for the characterization of orientational order in organic solids based on magic-angle spinning NMR spectroscopy is introduced. The method is related to the rotor-synchronized magic-angle spinning experiment proposed by Harbison and Spiess [Chem. Phys. Lett. 124, 128 (1986)], but exploits the anisotropy of the deuterium quadrupolar coupling instead of the carbon-13 chemical shielding anisotropy. Magic-angle spinning provides a sensitivity advantage over pseudostatic techniques; using the deuterium quadrupolar coupling makes the method applicable to systems that do not exhibit large carbon chemical shift anisotropies, such as aliphatic polymers. Due to the magnitude of the deuterium quadrupolar coupling, a large number of spinning sidebands can be reliably observed, allowing for a precise determination of the orientational distribution function. Experimental data are analyzed in terms of Wigner matrix basis functions as well as the conjugate orthogonal functions framework. Unidirectionally cold-drawn poly(ethylene) is used as an example to demonstrate the method.
Full text not available from this repository.
More information
Identifiers
Catalogue record
Export record
Altmetrics
Contributors
University divisions
- Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg)
- Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg) > Magnetic Resonance (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg) > Magnetic Resonance (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg) > Magnetic Resonance (pre 2018 reorg) - Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg)
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.