Utz, Marcel, Tomaselli, Marco, Ernst, Richard R. and Suter, Ulrich W. (1996) Orientation of molecular segments by plastic deformation of glassy polycarbonate. Macromolecules, 29 (8), 2909-2915. (doi:10.1021/ma951737p).
Abstract
Annealed, selectively 13C-labeled Bisphenol A polycarbonate samples were uniaxially compressed (compressive strain ca. 40%). One-dimensional static NMR spectra of the deformed samples were recorded at different orientations with respect to the magnetic field. The orientational distributions of the carbonate groups and the phenylene rings were determined through a fitting of the spectra by an expansion in Wigner rotation matrix elements. The data are explained quantitatively by an affine network-deformation model. The chains qualitatively behave as compressed random coils.
Full text not available from this repository.
More information
Identifiers
Catalogue record
Export record
Altmetrics
Contributors
University divisions
- Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg)
- Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg) > Magnetic Resonance (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg) > Magnetic Resonance (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg) > Magnetic Resonance (pre 2018 reorg) - Faculties (pre 2018 reorg) > Faculty of Natural and Environmental Sciences (pre 2018 reorg) > Chemistry (pre 2018 reorg)
Current Faculties > Faculty of Engineering and Physical Sciences > School of Chemistry > Chemistry (pre 2018 reorg)
School of Chemistry > Chemistry (pre 2018 reorg)
Download statistics
Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.