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Boundary Lubrication of Oxide Surfaces by Poly(L-lysine)-g-poly(ethylene glycol) (PLL-g-PEG) in Aqueous Media

Boundary Lubrication of Oxide Surfaces by Poly(L-lysine)-g-poly(ethylene glycol) (PLL-g-PEG) in Aqueous Media
Boundary Lubrication of Oxide Surfaces by Poly(L-lysine)-g-poly(ethylene glycol) (PLL-g-PEG) in Aqueous Media
In this work, we have explored the application of poly(L-lysine)-g-poly(ethylene glycol) (PLL-g-PEG) as an additive to improve the lubricating properties of water for metal-oxide-based tribo-systems. The adsorption behavior of the polymer onto both silicon oxide and iron oxide has been characterized by optical waveguide lightmode spectroscopy (OWLS). Several tribological approaches, including ultra-thin-film interferometry, the mini traction machine (MTM), and pin-on-disk tribometry, have been employed to characterize the frictional properties of the oxide tribo-systems in various contact regimes. The polymer appears to form a protective layer on the tribological interface in aqueous buffer solution and improves both the load-carrying and boundary-layer-lubrication properties of water
1023-8883
231-239
Lee, S.
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Muller, M.
359678c4-5d02-4ef8-b381-f31238f339d1
Ratoi, M.
cfeffe10-31ca-4630-8399-232c4bc2beff
Voros, J.
c358b4d5-ee7b-4d8d-98b6-3c7e5ffd0c10
Pasche, S.
5ba93338-2a97-43a7-8246-0edc3ac96665
De Paul, S.M.
1879ab36-3bb1-4ec5-97ca-d73431d9e502
Spikes, H.A.
e8d32127-b018-44b9-ad78-49e446ed590e
Textor, M.
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Spencer, N.D.
2650c9d3-b4a2-40aa-a5aa-f0f9da537b3c
Lee, S.
b9b22495-ff29-4546-a18e-27690662256e
Muller, M.
359678c4-5d02-4ef8-b381-f31238f339d1
Ratoi, M.
cfeffe10-31ca-4630-8399-232c4bc2beff
Voros, J.
c358b4d5-ee7b-4d8d-98b6-3c7e5ffd0c10
Pasche, S.
5ba93338-2a97-43a7-8246-0edc3ac96665
De Paul, S.M.
1879ab36-3bb1-4ec5-97ca-d73431d9e502
Spikes, H.A.
e8d32127-b018-44b9-ad78-49e446ed590e
Textor, M.
f76f9b2b-2823-488c-8b96-4605bc4d3311
Spencer, N.D.
2650c9d3-b4a2-40aa-a5aa-f0f9da537b3c

Lee, S., Muller, M., Ratoi, M., Voros, J., Pasche, S., De Paul, S.M., Spikes, H.A., Textor, M. and Spencer, N.D. (2003) Boundary Lubrication of Oxide Surfaces by Poly(L-lysine)-g-poly(ethylene glycol) (PLL-g-PEG) in Aqueous Media. Tribology Letters, 15 (3), 231-239. (doi:10.1023/A:1024861119372).

Record type: Article

Abstract

In this work, we have explored the application of poly(L-lysine)-g-poly(ethylene glycol) (PLL-g-PEG) as an additive to improve the lubricating properties of water for metal-oxide-based tribo-systems. The adsorption behavior of the polymer onto both silicon oxide and iron oxide has been characterized by optical waveguide lightmode spectroscopy (OWLS). Several tribological approaches, including ultra-thin-film interferometry, the mini traction machine (MTM), and pin-on-disk tribometry, have been employed to characterize the frictional properties of the oxide tribo-systems in various contact regimes. The polymer appears to form a protective layer on the tribological interface in aqueous buffer solution and improves both the load-carrying and boundary-layer-lubrication properties of water

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Published date: October 2003
Organisations: nCATS Group

Identifiers

Local EPrints ID: 356078
URI: http://eprints.soton.ac.uk/id/eprint/356078
ISSN: 1023-8883
PURE UUID: fcb21e3b-e47f-4226-af14-8ee6f1ba7d07
ORCID for M. Ratoi: ORCID iD orcid.org/0000-0001-8400-3054

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Date deposited: 25 Oct 2013 13:42
Last modified: 12 Nov 2024 02:45

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Contributors

Author: S. Lee
Author: M. Muller
Author: M. Ratoi ORCID iD
Author: J. Voros
Author: S. Pasche
Author: S.M. De Paul
Author: H.A. Spikes
Author: M. Textor
Author: N.D. Spencer

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