Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts
Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts
A novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-chemical characterisation, in combination with in-depth kinetic analysis have afforded profound insights into the nature of the active site for facilitating structure–property correlations.
12600-12605
Hinde, Christopher S.
08da9ba4-06f6-433c-a6f9-269441ffa557
Van Aswegen, Sivan
68316820-cf51-40bf-b85d-d30ba81ea594
Collins, Gillian
26450c2d-06de-4595-8568-6ba1dee14d77
Holmes, Justin D.
ecb7b5b3-fe4b-45e2-b85b-0dd7a3967a4c
Hor, T.S. Andy
927efbd5-178d-488f-a9a2-917bc2b6975c
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
21 September 2013
Hinde, Christopher S.
08da9ba4-06f6-433c-a6f9-269441ffa557
Van Aswegen, Sivan
68316820-cf51-40bf-b85d-d30ba81ea594
Collins, Gillian
26450c2d-06de-4595-8568-6ba1dee14d77
Holmes, Justin D.
ecb7b5b3-fe4b-45e2-b85b-0dd7a3967a4c
Hor, T.S. Andy
927efbd5-178d-488f-a9a2-917bc2b6975c
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Hinde, Christopher S., Van Aswegen, Sivan, Collins, Gillian, Holmes, Justin D., Hor, T.S. Andy and Raja, Robert
(2013)
Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts.
Dalton Transactions, 42 (35), .
(doi:10.1039/C3DT50606A).
(PMID:23698390)
Abstract
A novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-chemical characterisation, in combination with in-depth kinetic analysis have afforded profound insights into the nature of the active site for facilitating structure–property correlations.
Text
c3dt50606a.pdf
- Accepted Manuscript
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e-pub ahead of print date: 14 May 2013
Published date: 21 September 2013
Organisations:
Chemistry
Identifiers
Local EPrints ID: 356288
URI: http://eprints.soton.ac.uk/id/eprint/356288
ISSN: 0300-9246
PURE UUID: d21946a9-4a8d-480e-9981-4ccbb99d63be
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Date deposited: 17 Sep 2013 12:21
Last modified: 15 Mar 2024 03:26
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Contributors
Author:
Christopher S. Hinde
Author:
Sivan Van Aswegen
Author:
Gillian Collins
Author:
Justin D. Holmes
Author:
T.S. Andy Hor
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