The University of Southampton
University of Southampton Institutional Repository

Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts

Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts
Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts
A novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-chemical characterisation, in combination with in-depth kinetic analysis have afforded profound insights into the nature of the active site for facilitating structure–property correlations.
0300-9246
12600-12605
Hinde, Christopher S.
08da9ba4-06f6-433c-a6f9-269441ffa557
Van Aswegen, Sivan
68316820-cf51-40bf-b85d-d30ba81ea594
Collins, Gillian
26450c2d-06de-4595-8568-6ba1dee14d77
Holmes, Justin D.
ecb7b5b3-fe4b-45e2-b85b-0dd7a3967a4c
Hor, T.S. Andy
927efbd5-178d-488f-a9a2-917bc2b6975c
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Hinde, Christopher S.
08da9ba4-06f6-433c-a6f9-269441ffa557
Van Aswegen, Sivan
68316820-cf51-40bf-b85d-d30ba81ea594
Collins, Gillian
26450c2d-06de-4595-8568-6ba1dee14d77
Holmes, Justin D.
ecb7b5b3-fe4b-45e2-b85b-0dd7a3967a4c
Hor, T.S. Andy
927efbd5-178d-488f-a9a2-917bc2b6975c
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b

Hinde, Christopher S., Van Aswegen, Sivan, Collins, Gillian, Holmes, Justin D., Hor, T.S. Andy and Raja, Robert (2013) Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts. Dalton Transactions, 42 (35), 12600-12605. (doi:10.1039/C3DT50606A). (PMID:23698390)

Record type: Article

Abstract

A novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-chemical characterisation, in combination with in-depth kinetic analysis have afforded profound insights into the nature of the active site for facilitating structure–property correlations.

Text
c3dt50606a.pdf - Accepted Manuscript
Download (643kB)

More information

e-pub ahead of print date: 14 May 2013
Published date: 21 September 2013
Organisations: Chemistry

Identifiers

Local EPrints ID: 356288
URI: http://eprints.soton.ac.uk/id/eprint/356288
ISSN: 0300-9246
PURE UUID: d21946a9-4a8d-480e-9981-4ccbb99d63be
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 17 Sep 2013 12:21
Last modified: 18 Feb 2021 17:07

Export record

Altmetrics

Contributors

Author: Christopher S. Hinde
Author: Sivan Van Aswegen
Author: Gillian Collins
Author: Justin D. Holmes
Author: T.S. Andy Hor
Author: Robert Raja ORCID iD

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×