Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures
Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures
The ability to adroitly tailor acid-strength using specifically-engineered bimetallic nanoporous materials has been investigated with a view to exploiting their potential in solid-acid catalysed transformations. Further, it has been demonstrated that through site-specific interactions, extra-framework zinc ions can suitably modify the acidity of Brønsted acid sites, to stimulate diverse catalytic responses, when combined with isomorphously-substituted framework metal cations within porous architectures, for the Beckmann rearrangement of cyclohexanone oxime and in the isopropylation of benzene.
13288-13295
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Sun, Danni
b99cc371-82b3-4ac7-b83c-8cbc53434500
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Manzoli, Maela
a17ae924-77c3-47b3-8c3b-d1b29cac758a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
28 August 2013
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Sun, Danni
b99cc371-82b3-4ac7-b83c-8cbc53434500
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Manzoli, Maela
a17ae924-77c3-47b3-8c3b-d1b29cac758a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Potter, Matthew, Sun, Danni, Gianotti, Enrica, Manzoli, Maela and Raja, Robert
(2013)
Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures.
Physical Chemistry Chemical Physics, 15 (32), .
(doi:10.1039/C3CP51182K).
(PMID:23728183)
Abstract
The ability to adroitly tailor acid-strength using specifically-engineered bimetallic nanoporous materials has been investigated with a view to exploiting their potential in solid-acid catalysed transformations. Further, it has been demonstrated that through site-specific interactions, extra-framework zinc ions can suitably modify the acidity of Brønsted acid sites, to stimulate diverse catalytic responses, when combined with isomorphously-substituted framework metal cations within porous architectures, for the Beckmann rearrangement of cyclohexanone oxime and in the isopropylation of benzene.
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e-pub ahead of print date: 23 May 2013
Published date: 28 August 2013
Organisations:
Chemistry
Identifiers
Local EPrints ID: 356289
URI: http://eprints.soton.ac.uk/id/eprint/356289
ISSN: 1463-9076
PURE UUID: 45f821b2-70e4-45f0-add4-d63591af015d
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Date deposited: 17 Sep 2013 12:26
Last modified: 15 Mar 2024 03:26
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Author:
Danni Sun
Author:
Enrica Gianotti
Author:
Maela Manzoli
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