The University of Southampton
University of Southampton Institutional Repository

Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures

Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures
Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures
The ability to adroitly tailor acid-strength using specifically-engineered bimetallic nanoporous materials has been investigated with a view to exploiting their potential in solid-acid catalysed transformations. Further, it has been demonstrated that through site-specific interactions, extra-framework zinc ions can suitably modify the acidity of Brønsted acid sites, to stimulate diverse catalytic responses, when combined with isomorphously-substituted framework metal cations within porous architectures, for the Beckmann rearrangement of cyclohexanone oxime and in the isopropylation of benzene.
1463-9076
13288-13295
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Sun, Danni
b99cc371-82b3-4ac7-b83c-8cbc53434500
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Manzoli, Maela
a17ae924-77c3-47b3-8c3b-d1b29cac758a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b
Potter, Matthew
34dee7dc-2f62-4022-bb65-fc7b7fb526d2
Sun, Danni
b99cc371-82b3-4ac7-b83c-8cbc53434500
Gianotti, Enrica
2496d8d3-780f-4fe0-a43e-147e68331078
Manzoli, Maela
a17ae924-77c3-47b3-8c3b-d1b29cac758a
Raja, Robert
74faf442-38a6-4ac1-84f9-b3c039cb392b

Potter, Matthew, Sun, Danni, Gianotti, Enrica, Manzoli, Maela and Raja, Robert (2013) Investigating site-specific interactions and probing their role in modifying the acid-strength in framework architectures. Physical Chemistry Chemical Physics, 15 (32), 13288-13295. (doi:10.1039/C3CP51182K). (PMID:23728183)

Record type: Article

Abstract

The ability to adroitly tailor acid-strength using specifically-engineered bimetallic nanoporous materials has been investigated with a view to exploiting their potential in solid-acid catalysed transformations. Further, it has been demonstrated that through site-specific interactions, extra-framework zinc ions can suitably modify the acidity of Brønsted acid sites, to stimulate diverse catalytic responses, when combined with isomorphously-substituted framework metal cations within porous architectures, for the Beckmann rearrangement of cyclohexanone oxime and in the isopropylation of benzene.

Text
c3cp51182k.pdf - Author's Original
Download (816kB)
Text
__userfiles.soton.ac.uk_Users_nl2_mydesktop_Slabakova_c3cp51182k-ESI.pdf - Other
Download (464kB)

More information

e-pub ahead of print date: 23 May 2013
Published date: 28 August 2013
Organisations: Chemistry

Identifiers

Local EPrints ID: 356289
URI: http://eprints.soton.ac.uk/id/eprint/356289
ISSN: 1463-9076
PURE UUID: 45f821b2-70e4-45f0-add4-d63591af015d
ORCID for Matthew Potter: ORCID iD orcid.org/0000-0001-9849-3306
ORCID for Robert Raja: ORCID iD orcid.org/0000-0002-4161-7053

Catalogue record

Date deposited: 17 Sep 2013 12:26
Last modified: 18 Feb 2021 17:16

Export record

Altmetrics

Contributors

Author: Matthew Potter ORCID iD
Author: Danni Sun
Author: Enrica Gianotti
Author: Maela Manzoli
Author: Robert Raja ORCID iD

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×