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Synthesis of meso-substituted tetrabenzotriazaporphyrins: easy access to hybrid macrocycles

Synthesis of meso-substituted tetrabenzotriazaporphyrins: easy access to hybrid macrocycles
Synthesis of meso-substituted tetrabenzotriazaporphyrins: easy access to hybrid macrocycles
Up to now, hybrid structures that lie between the ubiquitous phthalocyanine and porphyrin scaffolds have been extremely difficult to prepare. A straightforward, high yielding synthesis of meso-derivatized tetrabenzotriazaporphyrins (see scheme) is described, thus unlocking access to this underdeveloped class of materials.
dyes/pigments, heterocycles, macrocyles, organic synthesis, porphyrinoids
1433-7851
Díaz-Moscoso, Alejandro
0add82f3-aaff-4875-b2d8-e25e29e7d59e
Tizzard, Graham J.
8474c0fa-40df-43a6-a662-7f3c4722dbf2
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Cammidge, Andrew N.
e7a6b5be-5613-416e-8f1a-40b4744ecf65
Díaz-Moscoso, Alejandro
0add82f3-aaff-4875-b2d8-e25e29e7d59e
Tizzard, Graham J.
8474c0fa-40df-43a6-a662-7f3c4722dbf2
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Cammidge, Andrew N.
e7a6b5be-5613-416e-8f1a-40b4744ecf65

Díaz-Moscoso, Alejandro, Tizzard, Graham J., Coles, Simon J. and Cammidge, Andrew N. (2013) Synthesis of meso-substituted tetrabenzotriazaporphyrins: easy access to hybrid macrocycles. Angewandte Chemie International Edition. (doi:10.1002/anie.201306151).

Record type: Article

Abstract

Up to now, hybrid structures that lie between the ubiquitous phthalocyanine and porphyrin scaffolds have been extremely difficult to prepare. A straightforward, high yielding synthesis of meso-derivatized tetrabenzotriazaporphyrins (see scheme) is described, thus unlocking access to this underdeveloped class of materials.

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More information

Published date: 4 October 2013
Keywords: dyes/pigments, heterocycles, macrocyles, organic synthesis, porphyrinoids
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences

Identifiers

Local EPrints ID: 356352
URI: http://eprints.soton.ac.uk/id/eprint/356352
ISSN: 1433-7851
PURE UUID: 490e0d5f-f82f-495b-a739-1169acc20a84
ORCID for Graham J. Tizzard: ORCID iD orcid.org/0000-0002-1577-5779
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 24 Sep 2013 13:13
Last modified: 18 Feb 2021 16:57

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