Detecting anthropogenic carbon dioxide uptake and ocean acidification in the North Atlantic Ocean
Detecting anthropogenic carbon dioxide uptake and ocean acidification in the North Atlantic Ocean
Fossil fuel use, cement manufacture and land-use changes are the primary sources of anthropogenic carbon dioxide (CO2) to the atmosphere, with the ocean absorbing approximately 30% (Sabine et al., 2004). Ocean uptake and chemical equilibration of anthropogenic CO2 with seawater results in a gradual reduction in seawater pH and saturation states (?) for calcium carbonate (CaCO3) minerals in a process termed ocean acidification. Assessing the present and future impact of ocean acidification on marine ecosystems requires detection of the multi-decadal rate of change across ocean basins and at ocean time-series sites. Here, we show the longest continuous record of ocean CO2 changes and ocean acidification in the North Atlantic subtropical gyre near Bermuda from 1983–2011. Dissolved inorganic carbon (DIC) and partial pressure of CO2 (pCO2) increased in surface seawater by ~40 ?mol kg?1 and ~50 ?atm (~20%), respectively. Increasing Revelle factor (?) values imply that the capacity of North Atlantic surface waters to absorb CO2 has also diminished. As indicators of ocean acidification, seawater pH decreased by ~0.05 (0.0017 yr?1) and ? values by ~7–8%. Such data provide critically needed multi-decadal information for assessing the North Atlantic Ocean CO2 sink and the pH changes that determine marine ecosystem responses to ocean acidification.
2509-2522
Bates, N.R.
954a83d6-8424-49e9-8acd-e606221c9c57
Best, M.H.P.
df4a1160-e1e1-43c6-a55f-2900043007cc
Neely, K.
777d27ca-6dc4-408e-9839-29c83230518a
Garley, R.
d23dffe7-041d-460b-b06a-ff103da9d388
Dickson, A.G.
8ae78eef-65fa-47fb-80e3-c8e1e4fa08eb
Johnson, R.J.
de7c575d-7078-460f-b305-8c4a7c248a8b
11 July 2012
Bates, N.R.
954a83d6-8424-49e9-8acd-e606221c9c57
Best, M.H.P.
df4a1160-e1e1-43c6-a55f-2900043007cc
Neely, K.
777d27ca-6dc4-408e-9839-29c83230518a
Garley, R.
d23dffe7-041d-460b-b06a-ff103da9d388
Dickson, A.G.
8ae78eef-65fa-47fb-80e3-c8e1e4fa08eb
Johnson, R.J.
de7c575d-7078-460f-b305-8c4a7c248a8b
Bates, N.R., Best, M.H.P., Neely, K., Garley, R., Dickson, A.G. and Johnson, R.J.
(2012)
Detecting anthropogenic carbon dioxide uptake and ocean acidification in the North Atlantic Ocean.
Biogeosciences, 9 (7), .
(doi:10.5194/bg-9-2509-2012).
Abstract
Fossil fuel use, cement manufacture and land-use changes are the primary sources of anthropogenic carbon dioxide (CO2) to the atmosphere, with the ocean absorbing approximately 30% (Sabine et al., 2004). Ocean uptake and chemical equilibration of anthropogenic CO2 with seawater results in a gradual reduction in seawater pH and saturation states (?) for calcium carbonate (CaCO3) minerals in a process termed ocean acidification. Assessing the present and future impact of ocean acidification on marine ecosystems requires detection of the multi-decadal rate of change across ocean basins and at ocean time-series sites. Here, we show the longest continuous record of ocean CO2 changes and ocean acidification in the North Atlantic subtropical gyre near Bermuda from 1983–2011. Dissolved inorganic carbon (DIC) and partial pressure of CO2 (pCO2) increased in surface seawater by ~40 ?mol kg?1 and ~50 ?atm (~20%), respectively. Increasing Revelle factor (?) values imply that the capacity of North Atlantic surface waters to absorb CO2 has also diminished. As indicators of ocean acidification, seawater pH decreased by ~0.05 (0.0017 yr?1) and ? values by ~7–8%. Such data provide critically needed multi-decadal information for assessing the North Atlantic Ocean CO2 sink and the pH changes that determine marine ecosystem responses to ocean acidification.
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Published date: 11 July 2012
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Creative Commons Attribution 3.0 License
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Ocean Biochemistry & Ecosystems
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Local EPrints ID: 356533
URI: http://eprints.soton.ac.uk/id/eprint/356533
ISSN: 1726-4170
PURE UUID: 88023a78-ac1c-42f8-b515-af6c1ba55132
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Date deposited: 06 Sep 2013 09:02
Last modified: 14 Mar 2024 14:50
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Author:
M.H.P. Best
Author:
K. Neely
Author:
R. Garley
Author:
A.G. Dickson
Author:
R.J. Johnson
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