Intercomparison of shipboard and moored CARIOCA buoy seawater fCO₂ measurements in the Sargasso Sea

Bates, Nicholas R., Merlivat, Liliane, Beaumont, Laurence and Pequignet, A.Christine (2000) Intercomparison of shipboard and moored CARIOCA buoy seawater fCO₂ measurements in the Sargasso Sea. Marine Chemistry, 72 (2-4), 239-255. (doi:10.1016/S0304-4203(00)00084-0).

Abstract

The ocean is an important sink for carbon and heat, yet high-resolution measurements of biogeochemical properties relevant to global climate change are being made only sporadically in the ocean at present. There is a growing need for automated, real-time, long-term measurements of CO₂ in the ocean using a network of sensors, strategically placed on ships, moorings, free-drifting buoys and autonomous remotely operated vehicles. The ground-truthing of new sensor technologies is a vital component of present and future efforts to monitor changes in the ocean carbon cycle and air–sea exchange of CO₂.

A comparison of a moored Carbon Interface Ocean Atmosphere (CARIOCA) buoy and shipboard fugacity of CO2 (fCO2) measurements was conducted in the western North Atlantic during two extended periods (>1 month) in 1997. The CARIOCA buoy was deployed on the Bermuda Testbed Mooring (BTM), which is located 5 km north of the site of the US Joint Global Ocean Flux Study (JGOFS) Bermuda Atlantic Time-series Study (BATS). The high frequency of sampling revealed that temperature and fCO₂ responded to physical forcing by the atmosphere on timescales from diurnal to 4–8 days. Concurrent with the deployments of the CARIOCA buoy, frequent measurements of surface fCO₂ were made from the R/V Weatherbird II during opportunistic visits to the BTM and BATS sites, providing a direct calibration of the CARIOCA buoy fCO₂ data. Although, the in situ ground-truthing of the CARIOCA buoy was complicated by diurnal processes, sub-mesoscale and fine-scale variability, the CARIOCA buoy fCO₂ data was accurate within 3±6 µatm of shipboard fCO₂ data for periods up to 50 days. Longer-term assessments were not possible due to the CARIOCA buoy breaking free of the BTM and drifting into waters with different fCO₂-temperature properties. Strategies are put forward for future calibration of other in situ sensors.

This record has no associated files available for download.

Contributors

Download statistics