Crystal engineering of brominated tectons: N-methyl-3,5-dibromopyridinium
iodide gives particularly short C–Br...I halogen bonding
Crystal engineering of brominated tectons: N-methyl-3,5-dibromopyridinium
iodide gives particularly short C–Br...I halogen bonding
The crystal matrix of N-methyl-3,5-dibromopyridinium iodide is constituted of infinite helices where the cation and the anion alternate and are bound by the second shortest reported C–BrI halogen bonding. The electron poor pyridinium scaffold is particularly effective in boosting the electron acceptor ability of bromine substituents.
760-763
Logothetis, Thomas A.
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Meyer, Franck
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Metrangolo, Pierangelo
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Pilati, Tullio
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Resnati, Giuseppe
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2004
Logothetis, Thomas A.
9f42a28f-0c36-4d47-a137-7a317acb0237
Meyer, Franck
4088b1ff-547a-4ac6-9e4b-7c4cfe109773
Metrangolo, Pierangelo
ed6f9ae5-24b4-4895-9155-5dc99aa9896f
Pilati, Tullio
5b45c798-1434-41ce-9274-06b2c0206a6e
Resnati, Giuseppe
04756490-614b-4705-a98b-052c4afebe9e
Logothetis, Thomas A., Meyer, Franck, Metrangolo, Pierangelo, Pilati, Tullio and Resnati, Giuseppe
(2004)
Crystal engineering of brominated tectons: N-methyl-3,5-dibromopyridinium
iodide gives particularly short C–Br...I halogen bonding.
New Journal of Chemistry, 28 (6), .
(doi:10.1039/B401421A).
Abstract
The crystal matrix of N-methyl-3,5-dibromopyridinium iodide is constituted of infinite helices where the cation and the anion alternate and are bound by the second shortest reported C–BrI halogen bonding. The electron poor pyridinium scaffold is particularly effective in boosting the electron acceptor ability of bromine substituents.
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NJC 2004, 28(6), 760-3.pdf
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Published date: 2004
Organisations:
Chemistry
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Local EPrints ID: 360735
URI: http://eprints.soton.ac.uk/id/eprint/360735
ISSN: 1144-0546
PURE UUID: b18450f1-7442-404e-a2e7-9403df28eef1
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Date deposited: 03 Jan 2014 15:07
Last modified: 15 Mar 2024 03:30
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Author:
Franck Meyer
Author:
Pierangelo Metrangolo
Author:
Tullio Pilati
Author:
Giuseppe Resnati
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