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Halogen bonding and pi-pi stacking control reactivity in the solid state

Halogen bonding and pi-pi stacking control reactivity in the solid state
Halogen bonding and pi-pi stacking control reactivity in the solid state
The halogen bonding and the pi-pi stacking interactions induce the noncovalent self-assembly of modules into photoreactive supramolecular architecture. The ?···? interaction pre-organizes the template, and the halogen bonding aligns the olefins to conform to the topochemical principle for photoreaction. The UV irradiation of the crystal resulted in a cyclization product with quantitative yield and stereospecificity.
0002-7863
4500-4501
Caronna, T.
e7d1a529-1342-401a-b3fc-072c0ac0a869
Liantonio, R.
93539ef8-f09d-4cee-9436-da916702af97
Logothetis, Thomas A.
9f42a28f-0c36-4d47-a137-7a317acb0237
Metrangolo, P.
44aa3f33-65ac-4e5f-b6ff-d6a5d9a48336
Pilati, T.
88acccce-16f5-45d6-ba30-0b8f82b51783
Resnati, G.
5b7996fc-4427-426e-862f-74fce6fbf87e
Caronna, T.
e7d1a529-1342-401a-b3fc-072c0ac0a869
Liantonio, R.
93539ef8-f09d-4cee-9436-da916702af97
Logothetis, Thomas A.
9f42a28f-0c36-4d47-a137-7a317acb0237
Metrangolo, P.
44aa3f33-65ac-4e5f-b6ff-d6a5d9a48336
Pilati, T.
88acccce-16f5-45d6-ba30-0b8f82b51783
Resnati, G.
5b7996fc-4427-426e-862f-74fce6fbf87e

Caronna, T., Liantonio, R., Logothetis, Thomas A., Metrangolo, P., Pilati, T. and Resnati, G. (2004) Halogen bonding and pi-pi stacking control reactivity in the solid state. Journal of the American Chemical Society, 126 (14), 4500-4501. (doi:10.1021/ja039884n).

Record type: Article

Abstract

The halogen bonding and the pi-pi stacking interactions induce the noncovalent self-assembly of modules into photoreactive supramolecular architecture. The ?···? interaction pre-organizes the template, and the halogen bonding aligns the olefins to conform to the topochemical principle for photoreaction. The UV irradiation of the crystal resulted in a cyclization product with quantitative yield and stereospecificity.

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Published date: 23 March 2004
Organisations: Chemistry
Learn more about Chemistry research

Identifiers

Local EPrints ID: 360739
URI: http://eprints.soton.ac.uk/id/eprint/360739
DOI: doi:10.1021/ja039884n
ISSN: 0002-7863
PURE UUID: e281cbc6-1c53-4e04-a672-adec5bff8b21
ORCID for Thomas A. Logothetis: ORCID iD orcid.org/0000-0002-3437-5287

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Date deposited: 03 Jan 2014 15:10
Last modified: 15 Mar 2024 03:30

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Contributors

Author: T. Caronna
Author: R. Liantonio
Author: Thomas A. Logothetis ORCID iD
Author: P. Metrangolo
Author: T. Pilati
Author: G. Resnati

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