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Remarkable scan rate dependence for a highly constrained dinuclear iron(ii) spin crossover complex with a wide thermal hysteresis loop

Remarkable scan rate dependence for a highly constrained dinuclear iron(ii) spin crossover complex with a wide thermal hysteresis loop
Remarkable scan rate dependence for a highly constrained dinuclear iron(ii) spin crossover complex with a wide thermal hysteresis loop
The abrupt [HS-HS] ? localized [HS-LS] spin crossovers of a new triazole-based diiron(II) complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (?T = 22 K by SQUID magnetometer in “settle” mode) and show a remarkable scan rate dependence of only the cooling branch, as revealed by detailed magnetic, DSC, and Mössbauer studies.
0002-7863
878-881
Kulmaczewski, Rafal
9af18579-178a-452a-aec3-adfec3288d70
Olguín, Juan
710148c5-0bbc-41dd-b3d9-54e076686984
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Feltham, Humphrey L. C.
343099f1-b760-408c-8ade-ef93e1a9a746
Jameson, Guy N. L.
6c485bbe-c1b1-4ea5-8cb5-973731cd24b9
Tallon, Jeffery L.
222eab00-1b08-441c-8f77-a0a099a4f0f0
Brooker, Sally
2ee9681a-3ff7-41be-88c5-681f66b953ef
Kulmaczewski, Rafal
9af18579-178a-452a-aec3-adfec3288d70
Olguín, Juan
710148c5-0bbc-41dd-b3d9-54e076686984
Kitchen, Jonathan A.
3999f5cb-d53e-4c51-b750-627bd2a1b9b6
Feltham, Humphrey L. C.
343099f1-b760-408c-8ade-ef93e1a9a746
Jameson, Guy N. L.
6c485bbe-c1b1-4ea5-8cb5-973731cd24b9
Tallon, Jeffery L.
222eab00-1b08-441c-8f77-a0a099a4f0f0
Brooker, Sally
2ee9681a-3ff7-41be-88c5-681f66b953ef

Kulmaczewski, Rafal, Olguín, Juan, Kitchen, Jonathan A., Feltham, Humphrey L. C., Jameson, Guy N. L., Tallon, Jeffery L. and Brooker, Sally (2014) Remarkable scan rate dependence for a highly constrained dinuclear iron(ii) spin crossover complex with a wide thermal hysteresis loop. Journal of the American Chemical Society, 136 (3), 878-881. (doi:10.1021/ja411563x).

Record type: Article

Abstract

The abrupt [HS-HS] ? localized [HS-LS] spin crossovers of a new triazole-based diiron(II) complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (?T = 22 K by SQUID magnetometer in “settle” mode) and show a remarkable scan rate dependence of only the cooling branch, as revealed by detailed magnetic, DSC, and Mössbauer studies.

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e-pub ahead of print date: 8 January 2014
Published date: 2014
Related URLs:
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences
Learn more about Chemistry research

Identifiers

Local EPrints ID: 362866
URI: http://eprints.soton.ac.uk/id/eprint/362866
DOI: doi:10.1021/ja411563x
ISSN: 0002-7863
PURE UUID: a56d72a7-f31d-4c4e-9ff7-65ba73da0bca
ORCID for Jonathan A. Kitchen: ORCID iD orcid.org/0000-0002-7139-5666

Catalogue record

Date deposited: 13 Mar 2014 11:21
Last modified: 14 Mar 2024 16:15

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Contributors

Author: Rafal Kulmaczewski
Author: Juan Olguín
Author: Jonathan A. Kitchen ORCID iD
Author: Humphrey L. C. Feltham
Author: Guy N. L. Jameson
Author: Jeffery L. Tallon
Author: Sally Brooker

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