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Coordination chemistry of the main group elements with phosphine, arsine and stibine ligands

Coordination chemistry of the main group elements with phosphine, arsine and stibine ligands
Coordination chemistry of the main group elements with phosphine, arsine and stibine ligands
Complexes of Group 2, 12, 13, 14, 15 and 16 elements with mono-, bi-, and poly-dentate phosphine and arsine ligands (and including the very few examples of stibine and bismuthine donor ligands) are described. Polydentate ligand complexes containing neutral or charged N, O, C, or S donor groups in addition to phosphino or arsino donor groups are included, but charged P or As (phosphides, arsenides, phosphinomethanides etc.) ligands are excluded. Emphasis is placed upon the X-ray structures, multinuclear NMR data and reactions. The major differences of this class of complexes compared to the familiar d-block phosphine/arsine complexes are discussed and rationalised in terms of the E–M bonding models. Literature coverage is focussed on the last 20 years, although key older work is also included where necessary for comparison purposes, and the article includes work published up to early 2013.

0010-8545
65-115
Burt, Jennifer
4f8a0b68-2fb3-4136-98ff-70dfe1acba98
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Burt, Jennifer
4f8a0b68-2fb3-4136-98ff-70dfe1acba98
Levason, William
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, Gillian
37d35b11-40ce-48c5-a68e-f6ce04cd4037

Burt, Jennifer, Levason, William and Reid, Gillian (2014) Coordination chemistry of the main group elements with phosphine, arsine and stibine ligands. Coordination Chemistry Reviews, 260, 65-115. (doi:10.1016/j.ccr.2013.09.020).

Record type: Article

Abstract

Complexes of Group 2, 12, 13, 14, 15 and 16 elements with mono-, bi-, and poly-dentate phosphine and arsine ligands (and including the very few examples of stibine and bismuthine donor ligands) are described. Polydentate ligand complexes containing neutral or charged N, O, C, or S donor groups in addition to phosphino or arsino donor groups are included, but charged P or As (phosphides, arsenides, phosphinomethanides etc.) ligands are excluded. Emphasis is placed upon the X-ray structures, multinuclear NMR data and reactions. The major differences of this class of complexes compared to the familiar d-block phosphine/arsine complexes are discussed and rationalised in terms of the E–M bonding models. Literature coverage is focussed on the last 20 years, although key older work is also included where necessary for comparison purposes, and the article includes work published up to early 2013.

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1-s2.0-S0010854513002191-main.pdf__tid=e1965ef2-3fed-11e4-a0bd-00000aab0f01&acdnat=1411125345_b618c67a088de2760938ea3a7367d7c8 - Version of Record
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e-pub ahead of print date: 10 October 2013
Published date: 1 February 2014
Organisations: Chemistry

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Local EPrints ID: 368632
URI: http://eprints.soton.ac.uk/id/eprint/368632
ISSN: 0010-8545
PURE UUID: 80af188b-5943-4a1f-a46a-6b05b39eebd4
ORCID for William Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for Gillian Reid: ORCID iD orcid.org/0000-0001-5349-3468

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Date deposited: 06 Sep 2014 12:33
Last modified: 18 Feb 2021 16:34

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Author: Jennifer Burt
Author: William Levason ORCID iD
Author: Gillian Reid ORCID iD

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