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An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60

An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60
An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60
New high-yielding synthetic routes to the small-molecule endofullerenes H2O@C60, D2O@C60 and H2@C60 are described. The use of high temperatures and pressures for the endohedral molecule incorporation are avoided. A new partial closure step using PPh3, and final suturing using a novel Diels–Alder/retro-Diels–Alder sequence are amongst the advances reported.
1359-7345
Krachmalnicoff, A.
72207594-b44a-4e0e-9378-d33e3bf492cd
Levitt, M.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3
Whitby, R.
45632236-ab00-4ad0-a02d-6209043e818b
Krachmalnicoff, A.
72207594-b44a-4e0e-9378-d33e3bf492cd
Levitt, M.
bcc5a80a-e5c5-4e0e-9a9a-249d036747c3
Whitby, R.
45632236-ab00-4ad0-a02d-6209043e818b

Krachmalnicoff, A., Levitt, M. and Whitby, R. (2014) An optimised scalable synthesis of H2O@C60and a new synthesis of H2@C60. Chemical Communications. (doi:10.1039/C4CC06198E).

Record type: Article

Abstract

New high-yielding synthetic routes to the small-molecule endofullerenes H2O@C60, D2O@C60 and H2@C60 are described. The use of high temperatures and pressures for the endohedral molecule incorporation are avoided. A new partial closure step using PPh3, and final suturing using a novel Diels–Alder/retro-Diels–Alder sequence are amongst the advances reported.

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Published date: 9 September 2014
Organisations: Chemistry

Identifiers

Local EPrints ID: 369192
URI: http://eprints.soton.ac.uk/id/eprint/369192
ISSN: 1359-7345
PURE UUID: 38ac9f0a-0fd2-4a03-b9c3-36721c3b99c2
ORCID for M. Levitt: ORCID iD orcid.org/0000-0001-9878-1180
ORCID for R. Whitby: ORCID iD orcid.org/0000-0002-9891-5502

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Date deposited: 30 Sep 2014 10:40
Last modified: 18 Feb 2021 16:56

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Contributors

Author: A. Krachmalnicoff
Author: M. Levitt ORCID iD
Author: R. Whitby ORCID iD

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