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A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks

A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks
A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks
The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn-12(III)] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.
1477-9226
10690
Frost, J. M.
50e6d008-efba-4c42-80be-6b140afc8259
Sanz, S.
1acc8c92-0a0e-4beb-bc82-3cf553148cb4
Rajeshkumar, T.
2f1a0a01-856a-4015-b4da-a2ecf9d6db01
Pitak, M. B.
eeb6a00f-2291-4376-830f-d30dfd607ed1
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Rajaraman, G.
1dbdc3ef-3e32-4007-99d5-f574916677d6
Wernsdorfer, W.
7cc6d1a2-3fb8-4b0c-a133-317bc968e6d2
Schnack, J.
b8049731-275d-49f4-a41c-cad8c5a29300
Lusby, P. J.
b11af6bd-85c0-4e65-86cf-b9e37e3e6265
Brechin, E. K.
5ba2c811-b2f4-4655-96d7-ac2dc8bad4f3
Frost, J. M.
50e6d008-efba-4c42-80be-6b140afc8259
Sanz, S.
1acc8c92-0a0e-4beb-bc82-3cf553148cb4
Rajeshkumar, T.
2f1a0a01-856a-4015-b4da-a2ecf9d6db01
Pitak, M. B.
eeb6a00f-2291-4376-830f-d30dfd607ed1
Coles, S. J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Rajaraman, G.
1dbdc3ef-3e32-4007-99d5-f574916677d6
Wernsdorfer, W.
7cc6d1a2-3fb8-4b0c-a133-317bc968e6d2
Schnack, J.
b8049731-275d-49f4-a41c-cad8c5a29300
Lusby, P. J.
b11af6bd-85c0-4e65-86cf-b9e37e3e6265
Brechin, E. K.
5ba2c811-b2f4-4655-96d7-ac2dc8bad4f3

Frost, J. M., Sanz, S., Rajeshkumar, T., Pitak, M. B., Coles, S. J., Rajaraman, G., Wernsdorfer, W., Schnack, J., Lusby, P. J. and Brechin, E. K. (2014) A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks. Dalton Transactions, 43 (28), 10690. (doi:10.1039/c4dt01469c).

Record type: Article

Abstract

The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [Mn-12(III)] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

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More information

Published date: 22 May 2014
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow, Chemistry, Faculty of Natural and Environmental Sciences

Identifiers

Local EPrints ID: 369316
URI: http://eprints.soton.ac.uk/id/eprint/369316
ISSN: 1477-9226
PURE UUID: 9d975b8f-c408-4165-8900-034b4bfd02d2
ORCID for M. B. Pitak: ORCID iD orcid.org/0000-0002-3680-7100
ORCID for S. J. Coles: ORCID iD orcid.org/0000-0001-8414-9272

Catalogue record

Date deposited: 30 Sep 2014 13:36
Last modified: 18 Feb 2021 16:53

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Contributors

Author: J. M. Frost
Author: S. Sanz
Author: T. Rajeshkumar
Author: M. B. Pitak ORCID iD
Author: S. J. Coles ORCID iD
Author: G. Rajaraman
Author: W. Wernsdorfer
Author: J. Schnack
Author: P. J. Lusby
Author: E. K. Brechin

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