New insights into geochemical behaviour in ancient marine carbonates (Upper Jurassic Ammonitico Rosso): novel proxies for interpreting sea-level dynamics and palaeoceanography

Coimbra, R., Immenhauser, A., Oloriz, F., Rodriguez-Galiano, V.F. and Chica-Olmo, M. (2014) New insights into geochemical behaviour in ancient marine carbonates (Upper Jurassic Ammonitico Rosso): novel proxies for interpreting sea-level dynamics and palaeoceanography. Sedimentology, 1-37. (doi:10.1111/sed.12148).

Abstract

Elemental concentrations in Phanerozoic sea water are known to fluctuate both in time and space. With regard to carbonates precipitated from marine fluids, elemental concentrations in the carbonate crystal lattice are affected by a complex array of equilibrium and non-equilibrium as well as post-depositional alteration processes. To assess the potential of carbonate elemental chemostratigraphy, seven Upper Jurassic sections were investigated along a proximal to distal transect across the south-east Iberian palaeomargin. The aim was to explore stratigraphic and spatial variations in calcium, strontium, magnesium, iron and manganese elemental abundances. The epicontinental geochemical record is influenced by the combination of continental runoff and a significant diagenetic overprint. In contrast, the epioceanic geochemical record agrees with reconstructed open marine sea water values, reflecting a moderate degree of syn-depositional to early marine pore water diagenesis. Establishing a fair degree of preservation of matrix micrite, a thorough statistical approach was applied and elemental associations tested for their environmental significance. Principal component and hierarchical cluster analyses revealed a persistent relation between carbonate magnesium, iron and strontium abundances. Processes related to early diagenetic nodulation in Ammonitico Rosso facies most probably account for the incorporation of these elements in the calcium carbonate lattice. The clear decoupling of carbonate manganese abundance with respect to the remaining elements is documented and related to high sea floor spreading rates and hydrothermal activity during the Late Jurassic. The investigation of potential time-fluctuation of geochemical patterns was approached through variogram computation. The observed temporal behaviour is most likely to be forced by relative sea-level dynamics, reflecting Late Jurassic palaeoceanographic conditions and potential planetary interactions. The data obtained in this study highlight the utility of elemental data from carbonate matrix micrites as geochemical proxies for studying the influence of remote trigger factors

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