The University of Southampton
University of Southampton Institutional Repository

Active-metal template synthesis of a molecular trefoil knot

Active-metal template synthesis of a molecular trefoil knot
Active-metal template synthesis of a molecular trefoil knot
Tying the knot: The marriage of catalysis and coordination chemistry enables two CuI ions (red; see picture) to work in partnership for the synthesis of a molecular trefoil knot. One ion entangles an acyclic building block to create a loop in the ligand, and the other gathers the ligand's reactive end-groups, threads the loop, and catalyzes the covalent capture of the knotted architecture by an alkyne–azide “click” reaction.
1433-7851
12280-12284
Barran, Perdita E.
108a9d6f-ea25-4864-be0b-ef843ee59179
Cole, Harriet L.
e3c0d93a-c7fb-40bb-b4b8-932fa149f9f2
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Leigh, David A.
826353b6-267f-44cd-a7e7-adf0c34f66c9
McGonigal, Paul R.
c76f3367-e206-42ae-b433-dd5fa6473142
Symes, Mark D.
c4bdd59d-9323-425f-8bb6-55259c4b9551
Wu, Jhenyi
edb8091f-9636-4d6a-a5f7-87abf825d103
Zengerle, Michael
e413419c-1c98-4234-bec6-a5ba024f22f1
Barran, Perdita E.
108a9d6f-ea25-4864-be0b-ef843ee59179
Cole, Harriet L.
e3c0d93a-c7fb-40bb-b4b8-932fa149f9f2
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Leigh, David A.
826353b6-267f-44cd-a7e7-adf0c34f66c9
McGonigal, Paul R.
c76f3367-e206-42ae-b433-dd5fa6473142
Symes, Mark D.
c4bdd59d-9323-425f-8bb6-55259c4b9551
Wu, Jhenyi
edb8091f-9636-4d6a-a5f7-87abf825d103
Zengerle, Michael
e413419c-1c98-4234-bec6-a5ba024f22f1

Barran, Perdita E., Cole, Harriet L., Goldup, Stephen M., Leigh, David A., McGonigal, Paul R., Symes, Mark D., Wu, Jhenyi and Zengerle, Michael (2011) Active-metal template synthesis of a molecular trefoil knot. Angewandte Chemie International Edition, 50 (51), 12280-12284. (doi:10.1002/anie.201105012). (PMID:21919173)

Record type: Article

Abstract

Tying the knot: The marriage of catalysis and coordination chemistry enables two CuI ions (red; see picture) to work in partnership for the synthesis of a molecular trefoil knot. One ion entangles an acyclic building block to create a loop in the ligand, and the other gathers the ligand's reactive end-groups, threads the loop, and catalyzes the covalent capture of the knotted architecture by an alkyne–azide “click” reaction.

Full text not available from this repository.

More information

Published date: 14 September 2011
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 370654
URI: https://eprints.soton.ac.uk/id/eprint/370654
ISSN: 1433-7851
PURE UUID: 25068fad-39ba-4fed-9c9e-91243b0154c6
ORCID for Stephen M. Goldup: ORCID iD orcid.org/0000-0003-3781-0464

Catalogue record

Date deposited: 03 Nov 2014 13:19
Last modified: 05 Nov 2019 01:35

Export record

Altmetrics

Contributors

Author: Perdita E. Barran
Author: Harriet L. Cole
Author: David A. Leigh
Author: Paul R. McGonigal
Author: Mark D. Symes
Author: Jhenyi Wu
Author: Michael Zengerle

University divisions

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of https://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×