Macrocycle size matters: “small” functionalized rotaxanes in excellent yield using the CuAAC active template approach
Macrocycle size matters: “small” functionalized rotaxanes in excellent yield using the CuAAC active template approach
By shrinking the macrocycle in the CuAAC active template reaction not only is it demonstrated to be possible to use smaller macrocycles, but, surprisingly, that smaller macrocycles lead to higher yields of rotaxane product. The synthesis of “small” functionalized [2]rotaxanes showcases this as a method for the production of materials with potential applications in molecular electronics, drug delivery, sensing, and enantioselective catalysis.
4151-4155
Lahlali, Hicham
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Jobe, Kajally
ab190c46-b176-4fa8-8e22-56ff9c75a526
Watkinson, Michael
7405d50a-0e9d-4b31-8e23-0a3198eb1abd
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
1 April 2011
Lahlali, Hicham
45d4f6b0-6bf0-4a9c-bf1d-4b1cd89518cc
Jobe, Kajally
ab190c46-b176-4fa8-8e22-56ff9c75a526
Watkinson, Michael
7405d50a-0e9d-4b31-8e23-0a3198eb1abd
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Lahlali, Hicham, Jobe, Kajally, Watkinson, Michael and Goldup, Stephen M.
(2011)
Macrocycle size matters: “small” functionalized rotaxanes in excellent yield using the CuAAC active template approach.
Angewandte Chemie International Edition, 50 (18), .
(doi:10.1002/anie.201100415).
(PMID:21462287)
Abstract
By shrinking the macrocycle in the CuAAC active template reaction not only is it demonstrated to be possible to use smaller macrocycles, but, surprisingly, that smaller macrocycles lead to higher yields of rotaxane product. The synthesis of “small” functionalized [2]rotaxanes showcases this as a method for the production of materials with potential applications in molecular electronics, drug delivery, sensing, and enantioselective catalysis.
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Published date: 1 April 2011
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
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Local EPrints ID: 370655
URI: http://eprints.soton.ac.uk/id/eprint/370655
ISSN: 1433-7851
PURE UUID: 7865d2dd-645f-456e-9aad-ffe77b2dd548
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Date deposited: 03 Nov 2014 13:22
Last modified: 14 Mar 2024 18:20
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Author:
Hicham Lahlali
Author:
Kajally Jobe
Author:
Michael Watkinson
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