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Unusual mechanistic course of some NHC-mediated transesterifications

Unusual mechanistic course of some NHC-mediated transesterifications
Unusual mechanistic course of some NHC-mediated transesterifications
During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.
1523-7060
1643-1646
Pignataro, Luca
eec968a2-fc84-4ff3-87eb-361e09767be1
Papalia, Teresa
aefc1ac2-5ca4-4feb-aee7-43646e835a2d
Slawin, Alexandra M.Z.
45b99a30-c91c-4306-be37-6b7b0ec0affd
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Pignataro, Luca
eec968a2-fc84-4ff3-87eb-361e09767be1
Papalia, Teresa
aefc1ac2-5ca4-4feb-aee7-43646e835a2d
Slawin, Alexandra M.Z.
45b99a30-c91c-4306-be37-6b7b0ec0affd
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937

Pignataro, Luca, Papalia, Teresa, Slawin, Alexandra M.Z. and Goldup, Stephen M. (2009) Unusual mechanistic course of some NHC-mediated transesterifications. Organic Letters, 11 (7), 1643-1646. (doi:10.1021/ol900257t). (PMID:19320507)

Record type: Article

Abstract

During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.

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More information

Published date: 9 March 2009
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 370663
URI: http://eprints.soton.ac.uk/id/eprint/370663
DOI: doi:10.1021/ol900257t
ISSN: 1523-7060
PURE UUID: 67ff2392-ddd6-42a3-ab04-2f9a6984a52c
ORCID for Stephen M. Goldup: ORCID iD orcid.org/0000-0003-3781-0464

Catalogue record

Date deposited: 03 Nov 2014 13:51
Last modified: 14 Mar 2024 18:20

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Contributors

Author: Luca Pignataro
Author: Teresa Papalia
Author: Alexandra M.Z. Slawin
Author: Stephen M. Goldup ORCID iD

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