A catalytic palladium active-metal template pathway to [2]rotaxanes
A catalytic palladium active-metal template pathway to [2]rotaxanes
A multitasking template: [2]Rotaxanes have been synthesized with the help of a palladium active-metal template, which acts as both a template for threading and a catalyst for covalent-bond formation (see scheme). The synthesis is high yielding, operates under mild conditions, and is catalytic in palladium.
C-C coupling, homogeneous catalysis, palladium, rotaxanes, template synthesis
5709-5713
Berná, José
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Crowley, James D.
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Goldup, Stephen M.
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Hänni, Kevin D.
cebbe497-a98d-4b6b-8f26-0489cc7a94de
Lee, Ai-Lan
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Leigh, David A.
826353b6-267f-44cd-a7e7-adf0c34f66c9
23 July 2007
Berná, José
b5dcd6e7-4598-42ff-a3a2-728c4d49fc2d
Crowley, James D.
2d5e4e7f-b835-496a-a7db-e1a1856226db
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Hänni, Kevin D.
cebbe497-a98d-4b6b-8f26-0489cc7a94de
Lee, Ai-Lan
df4cd6d7-08ae-498d-b9e7-26e3449155d3
Leigh, David A.
826353b6-267f-44cd-a7e7-adf0c34f66c9
Berná, José, Crowley, James D., Goldup, Stephen M., Hänni, Kevin D., Lee, Ai-Lan and Leigh, David A.
(2007)
A catalytic palladium active-metal template pathway to [2]rotaxanes.
Angewandte Chemie International Edition, 46 (30), .
(doi:10.1002/anie.200701678).
Abstract
A multitasking template: [2]Rotaxanes have been synthesized with the help of a palladium active-metal template, which acts as both a template for threading and a catalyst for covalent-bond formation (see scheme). The synthesis is high yielding, operates under mild conditions, and is catalytic in palladium.
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e-pub ahead of print date: 23 July 2007
Published date: 23 July 2007
Keywords:
C-C coupling, homogeneous catalysis, palladium, rotaxanes, template synthesis
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 370669
URI: http://eprints.soton.ac.uk/id/eprint/370669
ISSN: 1433-7851
PURE UUID: 0d72803d-ac0a-4f21-8257-73ab6cfc29ae
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Date deposited: 03 Nov 2014 16:50
Last modified: 14 Mar 2024 18:20
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Contributors
Author:
José Berná
Author:
James D. Crowley
Author:
Kevin D. Hänni
Author:
Ai-Lan Lee
Author:
David A. Leigh
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