[FeFe]-hydrogenase synthetic mimics based on peri-substituted dichalcogenides

Figliola, Carlotta, Male, Louise, Horton, Peter N., Pitak, Mateusz B., Coles, Simon J., Horswell, Sarah L. and Grainger, Richard S. (2014) [FeFe]-hydrogenase synthetic mimics based on peri-substituted dichalcogenides. Organometallics, 33 (17), 4449-4460. (doi:10.1021/om500683p).

Abstract

Eight dithiolato-, diselenolato-, and mixed S,Se-Fe-2(CO)(6) complexes based on pen-substituted naphthalene and phenanthrene dichalcogenides are prepared by oxidative insertion of Fe-3(CO)(12) into the dichalcogen bonds of 2,7-dimethoxynaphtho[1,8cd][1,2]dithiole, three naphtho[1,8-cd][1,2]diselenoles, two naphtho[1,8-cd][1,2]thiaselenoles, phenanthro[1,10-cd][1,2]dithiole, and phenanthro[1,10-cd] [1,2]diselenole. Complexes are characterized by H-1, C-13 NMR, UV/vis, and IR spectroscopy and by X-ray analysis. The effect of replacing sulfur with selenium, incorporating electron-donating groups (2,7-di-ten-butyl, 2,7-climethoxy) on the naphthalene ring system, and changing the degree of conjugation in the aromatic backbone (naphthalene vs phenanthrene) on the reduction potential is evaluated by cyclic voltammetry. The electrocatalytic activity of these [FeFe]-hydrogenase synthetic mimics for proton reduction in the presence of increasing concentrations of p-TsOH is investigated. Diselenolate-based [FeFe]-complexes show enhanced catalytic activity for proton reduction compared with their sulfur congeners

This record has no associated files available for download.

Contributors

Author: Peter N. Horton

Author: Mateusz B. Pitak

Author: Simon J. Coles

Download statistics