Anion complexation, transport and structural studies of a series of bis-methylurea compounds
Anion complexation, transport and structural studies of a series of bis-methylurea compounds
A new family of bis-methylureas (L1–L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1 : 1 to 1 : 3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl? transport across membranes.
2138-2149
Olivari, Martina
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Montis, Riccardo
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Karagiannidis, Louise E.
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Horton, Peter N.
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Mapp, Lucy K.
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Coles, Simon J.
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Light, Mark E.
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Gale, Philip A.
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Caltagirone, Claudia
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1 December 2015
Olivari, Martina
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Montis, Riccardo
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Karagiannidis, Louise E.
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Horton, Peter N.
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Mapp, Lucy K.
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Coles, Simon J.
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Light, Mark E.
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Gale, Philip A.
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Caltagirone, Claudia
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Olivari, Martina, Montis, Riccardo, Karagiannidis, Louise E., Horton, Peter N., Mapp, Lucy K., Coles, Simon J., Light, Mark E., Gale, Philip A. and Caltagirone, Claudia
(2015)
Anion complexation, transport and structural studies of a series of bis-methylurea compounds.
Dalton Transactions, 44 (5), .
(doi:10.1039/c4dt02893g).
Abstract
A new family of bis-methylureas (L1–L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1 : 1 to 1 : 3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl? transport across membranes.
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Anion complexation, transport and structural studies of a series of bis methylurea compounds.docx
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Accepted/In Press date: 29 November 2014
e-pub ahead of print date: 2015
Published date: 1 December 2015
Organisations:
Organic Chemistry: Synthesis, Catalysis and Flow
Identifiers
Local EPrints ID: 373802
URI: http://eprints.soton.ac.uk/id/eprint/373802
ISSN: 0300-9246
PURE UUID: e9d34af4-4d56-457a-bfdb-3125fcd08375
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Date deposited: 02 Feb 2015 11:52
Last modified: 15 Mar 2024 03:06
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Contributors
Author:
Martina Olivari
Author:
Riccardo Montis
Author:
Louise E. Karagiannidis
Author:
Peter N. Horton
Author:
Lucy K. Mapp
Author:
Philip A. Gale
Author:
Claudia Caltagirone
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