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Anion complexation, transport and structural studies of a series of bis-methylurea compounds

Anion complexation, transport and structural studies of a series of bis-methylurea compounds
Anion complexation, transport and structural studies of a series of bis-methylurea compounds
A new family of bis-methylureas (L1–L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1 : 1 to 1 : 3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl? transport across membranes.
0300-9246
2138-2149
Olivari, Martina
1c804576-a704-4fed-be7b-be4841bfc2cd
Montis, Riccardo
11e15e46-6671-4ed0-9457-db82828bcdc7
Karagiannidis, Louise E.
625706f1-9870-43dd-9ee1-b981c60562b4
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Mapp, Lucy K.
91905fb2-a833-41b6-a0ac-b08b8a2fc2ce
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Caltagirone, Claudia
9148afed-6af0-4fcd-b30e-daa3d7765dc0
Olivari, Martina
1c804576-a704-4fed-be7b-be4841bfc2cd
Montis, Riccardo
11e15e46-6671-4ed0-9457-db82828bcdc7
Karagiannidis, Louise E.
625706f1-9870-43dd-9ee1-b981c60562b4
Horton, Peter N.
154c8930-bfc3-495b-ad4a-8a278d5da3a5
Mapp, Lucy K.
91905fb2-a833-41b6-a0ac-b08b8a2fc2ce
Coles, Simon J.
3116f58b-c30c-48cf-bdd5-397d1c1fecf8
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Caltagirone, Claudia
9148afed-6af0-4fcd-b30e-daa3d7765dc0

Olivari, Martina, Montis, Riccardo, Karagiannidis, Louise E., Horton, Peter N., Mapp, Lucy K., Coles, Simon J., Light, Mark E., Gale, Philip A. and Caltagirone, Claudia (2015) Anion complexation, transport and structural studies of a series of bis-methylurea compounds. Dalton Transactions, 44 (5), 2138-2149. (doi:10.1039/c4dt02893g).

Record type: Article

Abstract

A new family of bis-methylureas (L1–L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied. From the solid state studies it has emerged that various conformations can be adopted by the receptors allowing the isolation of complexes of different stoichiometries (from 1 : 1 to 1 : 3). The transport studies highlighted the possibility to use bis-methylureas to mediate Cl? transport across membranes.

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Anion complexation, transport and structural studies of a series of bis methylurea compounds.docx - Accepted Manuscript
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More information

Accepted/In Press date: 29 November 2014
e-pub ahead of print date: 2015
Published date: 1 December 2015
Organisations: Organic Chemistry: Synthesis, Catalysis and Flow

Identifiers

Local EPrints ID: 373802
URI: https://eprints.soton.ac.uk/id/eprint/373802
ISSN: 0300-9246
PURE UUID: e9d34af4-4d56-457a-bfdb-3125fcd08375
ORCID for Peter N. Horton: ORCID iD orcid.org/0000-0001-8886-2016
ORCID for Simon J. Coles: ORCID iD orcid.org/0000-0001-8414-9272
ORCID for Mark E. Light: ORCID iD orcid.org/0000-0002-0585-0843
ORCID for Philip A. Gale: ORCID iD orcid.org/0000-0001-9751-4910

Catalogue record

Date deposited: 02 Feb 2015 11:52
Last modified: 20 Jul 2019 01:10

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