The University of Southampton
University of Southampton Institutional Repository

A practical synthesis of a high-loading solid-supported IBX amide for the oxidation of alcohols

A practical synthesis of a high-loading solid-supported IBX amide for the oxidation of alcohols
A practical synthesis of a high-loading solid-supported IBX amide for the oxidation of alcohols
A straightforward three-step synthesis of a solid-supported IBX amide resin was achieved using inexpensive and commercially available 2-iodobenzoic acid chloride and Merrifield resin. A high apparent loading of 0.63 mmol g?1 was obtained. Oxidation of a range of alcohols to the corresponding carbonyl compounds proved very straightforward using 1.2 equiv of the resin. Recycling of the resin was also possible with minimal loss of activity after two reoxidations.
341-351
Lecarpentier, Patrick
cc040af5-614c-45e9-bc64-8b14cde34e8e
Crosignani, Stefano
aaa5cc3f-0b82-4d33-af01-59115c8bdff5
Linclau, Bruno
19b9cacd-b8e8-4c65-af36-6352cade84ba
Lecarpentier, Patrick
cc040af5-614c-45e9-bc64-8b14cde34e8e
Crosignani, Stefano
aaa5cc3f-0b82-4d33-af01-59115c8bdff5
Linclau, Bruno
19b9cacd-b8e8-4c65-af36-6352cade84ba

Lecarpentier, Patrick, Crosignani, Stefano and Linclau, Bruno (2005) A practical synthesis of a high-loading solid-supported IBX amide for the oxidation of alcohols. Molecular Diversity, 9 (4), 341-351. (doi:10.1007/s11030-005-8105-2).

Record type: Article

Abstract

A straightforward three-step synthesis of a solid-supported IBX amide resin was achieved using inexpensive and commercially available 2-iodobenzoic acid chloride and Merrifield resin. A high apparent loading of 0.63 mmol g?1 was obtained. Oxidation of a range of alcohols to the corresponding carbonyl compounds proved very straightforward using 1.2 equiv of the resin. Recycling of the resin was also possible with minimal loss of activity after two reoxidations.

Full text not available from this repository.

More information

Published date: 2005

Identifiers

Local EPrints ID: 37576
URI: http://eprints.soton.ac.uk/id/eprint/37576
PURE UUID: 48f32a33-e555-4745-8320-4c2702b9b1c0
ORCID for Bruno Linclau: ORCID iD orcid.org/0000-0001-8762-0170

Catalogue record

Date deposited: 24 May 2006
Last modified: 07 Oct 2020 07:54

Export record

Altmetrics

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Atom RSS 1.0 RSS 2.0

Contact ePrints Soton: eprints@soton.ac.uk

ePrints Soton supports OAI 2.0 with a base URL of http://eprints.soton.ac.uk/cgi/oai2

This repository has been built using EPrints software, developed at the University of Southampton, but available to everyone to use.

We use cookies to ensure that we give you the best experience on our website. If you continue without changing your settings, we will assume that you are happy to receive cookies on the University of Southampton website.

×