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Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex

Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex
Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex
We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers
1359-7345
3832-3834
Groombridge, Benjamin J.
b6912cd4-3b8e-4ef5-b722-5a99d8d83ba7
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Larrosa, Igor
6ab25161-9d87-4f15-8559-0c0e59810989
Groombridge, Benjamin J.
b6912cd4-3b8e-4ef5-b722-5a99d8d83ba7
Goldup, Stephen M.
0a93eedd-98bb-42c1-a963-e2815665e937
Larrosa, Igor
6ab25161-9d87-4f15-8559-0c0e59810989

Groombridge, Benjamin J., Goldup, Stephen M. and Larrosa, Igor (2015) Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd–NHC complex. Chemical Communications, 51 (18), 3832-3834. (doi:10.1039/C4CC08920K).

Record type: Article

Abstract

We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers

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Accepted/In Press date: 20 January 2015
Published date: 4 February 2015
Organisations: Organic Chemistry: SCF

Identifiers

Local EPrints ID: 376037
URI: http://eprints.soton.ac.uk/id/eprint/376037
DOI: doi:10.1039/C4CC08920K
ISSN: 1359-7345
PURE UUID: 9960eaf0-3b0d-4288-b8e2-c7ffc71c922b
ORCID for Stephen M. Goldup: ORCID iD orcid.org/0000-0003-3781-0464

Catalogue record

Date deposited: 23 Apr 2015 09:10
Last modified: 14 Mar 2024 19:37

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Contributors

Author: Benjamin J. Groombridge
Author: Stephen M. Goldup ORCID iD
Author: Igor Larrosa

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